data_26891 ####################### # Entry information # ####################### save_entry_information _Entry.Sf_category entry_information _Entry.Sf_framecode entry_information _Entry.ID 26891 _Entry.Title ; Solution and solid-state NMR studies of soluble tissue factor ; _Entry.Type macromolecule _Entry.Version_type original _Entry.Submission_date 2016-09-08 _Entry.Accession_date 2016-09-08 _Entry.Last_release_date 2016-10-04 _Entry.Original_release_date 2016-10-04 _Entry.Origination author _Entry.NMR_STAR_version 3.1.2.6 _Entry.Original_NMR_STAR_version 3.1 _Entry.Experimental_method NMR _Entry.Experimental_method_subtype SOLID-STATE _Entry.Details . _Entry.BMRB_internal_directory_name . loop_ _Entry_author.Ordinal _Entry_author.Given_name _Entry_author.Family_name _Entry_author.First_initial _Entry_author.Middle_initials _Entry_author.Family_title _Entry_author.ORCID _Entry_author.Entry_ID 1 Kristin Nuzzio . M. . . 26891 2 Eric Watt . D. . . 26891 3 John Boettcher . M. . . 26891 4 Joshua Gajsiewicz . M. . . 26891 5 James Morrissey . H. . . 26891 6 Chad Rienstra . M. . . 26891 stop_ loop_ _Data_set.Type _Data_set.Count _Data_set.Entry_ID spectral_peak_list 5 26891 stop_ loop_ _Release.Release_number _Release.Format_type _Release.Format_version _Release.Date _Release.Submission_date _Release.Type _Release.Author _Release.Detail _Release.Entry_ID 1 . . 2016-10-04 . original BMRB . 26891 stop_ save_ ############### # Citations # ############### save_entry_citation _Citation.Sf_category citations _Citation.Sf_framecode entry_citation _Citation.Entry_ID 26891 _Citation.ID 1 _Citation.Class 'entry citation' _Citation.CAS_abstract_code . _Citation.MEDLINE_UI_code . _Citation.DOI . _Citation.PubMed_ID 27657719 _Citation.Full_citation . _Citation.Title ; High-Resolution NMR Studies of Human Tissue Factor ; _Citation.Status published _Citation.Type journal _Citation.Journal_abbrev 'PLOS ONE' _Citation.Journal_name_full . _Citation.Journal_volume 11 _Citation.Journal_issue 9 _Citation.Journal_ASTM . _Citation.Journal_ISSN . _Citation.Journal_CSD . _Citation.Book_title . _Citation.Book_chapter_title . _Citation.Book_volume . _Citation.Book_series . _Citation.Book_publisher . _Citation.Book_publisher_city . _Citation.Book_ISBN . _Citation.Conference_title . _Citation.Conference_site . _Citation.Conference_state_province . _Citation.Conference_country . _Citation.Conference_start_date . _Citation.Conference_end_date . _Citation.Conference_abstract_number . _Citation.Thesis_institution . _Citation.Thesis_institution_city . _Citation.Thesis_institution_country . _Citation.WWW_URL . _Citation.Page_first e0163206 _Citation.Page_last e0163206 _Citation.Year 2016 _Citation.Details . loop_ _Citation_author.Ordinal _Citation_author.Given_name _Citation_author.Family_name _Citation_author.First_initial _Citation_author.Middle_initials _Citation_author.Family_title _Citation_author.ORCID _Citation_author.Entry_ID _Citation_author.Citation_ID 1 Kristin Nuzzio . M. . . 26891 1 2 Eric Watt . D. . . 26891 1 3 John Boettcher . M. . . 26891 1 4 Joshua Gajsiewicz . M. . . 26891 1 5 James Morrissey . H. . . 26891 1 6 Chad Rienstra . M. . . 26891 1 stop_ loop_ _Citation_keyword.Keyword _Citation_keyword.Entry_ID _Citation_keyword.Citation_ID 'blood coagulation' 26891 1 'solid-state NMR' 26891 1 'soluble tissue factor' 26891 1 'solution NMR' 26891 1 stop_ save_ ############################################# # Molecular system (assembly) description # ############################################# save_assembly _Assembly.Sf_category assembly _Assembly.Sf_framecode assembly _Assembly.Entry_ID 26891 _Assembly.ID 1 _Assembly.Name 'sTF monomer' _Assembly.BMRB_code . _Assembly.Number_of_components . _Assembly.Organic_ligands . _Assembly.Metal_ions . _Assembly.Non_standard_bonds . _Assembly.Ambiguous_conformational_states . _Assembly.Ambiguous_chem_comp_sites . _Assembly.Molecules_in_chemical_exchange . _Assembly.Paramagnetic no _Assembly.Thiol_state . _Assembly.Molecular_mass . _Assembly.Enzyme_commission_number . _Assembly.Details . _Assembly.DB_query_date . _Assembly.DB_query_revised_last_date . loop_ _Entity_assembly.ID _Entity_assembly.Entity_assembly_name _Entity_assembly.Entity_ID _Entity_assembly.Entity_label _Entity_assembly.Asym_ID _Entity_assembly.PDB_chain_ID _Entity_assembly.Experimental_data_reported _Entity_assembly.Physical_state _Entity_assembly.Conformational_isomer _Entity_assembly.Chemical_exchange_state _Entity_assembly.Magnetic_equivalence_group_code _Entity_assembly.Role _Entity_assembly.Details _Entity_assembly.Entry_ID _Entity_assembly.Assembly_ID 1 'sTF monomer' 1 $Extracellular_domain_of_tissue_factor A . yes native no no . . . 26891 1 stop_ save_ #################################### # Biological polymers and ligands # #################################### save_Extracellular_domain_of_tissue_factor _Entity.Sf_category entity _Entity.Sf_framecode Extracellular_domain_of_tissue_factor _Entity.Entry_ID 26891 _Entity.ID 1 _Entity.BMRB_code . _Entity.Name Extracellular_domain_of_tissue_factor _Entity.Type polymer _Entity.Polymer_common_type . _Entity.Polymer_type polypeptide(L) _Entity.Polymer_type_details . _Entity.Polymer_strand_ID . _Entity.Polymer_seq_one_letter_code_can . _Entity.Polymer_seq_one_letter_code ; ATTNTVAAYNLTWKSTNFKT ILEWEPKPVNQVYTVQISTK SGDWKSKCFYTTDTECDLTD EIVKDVKQTYLARVFSYPAG NVESTGSAGEPLYENSPEFT PYLETNLGQPTIQSFEQVGT KVNVTVEDERTLVRRNNTFL SLRDVFGKDLIYTLYYWKSS SSGKKTAKTNTNEFLIDVDK GENYCFSVQAVIPSRTVNRK STDSPVECMGQEKGEFREGG AAGHHHHHH ; _Entity.Target_identifier . _Entity.Polymer_author_defined_seq . _Entity.Polymer_author_seq_details . _Entity.Ambiguous_conformational_states no _Entity.Ambiguous_chem_comp_sites no _Entity.Nstd_monomer no _Entity.Nstd_chirality no _Entity.Nstd_linkage no _Entity.Nonpolymer_comp_ID . _Entity.Nonpolymer_comp_label . _Entity.Number_of_monomers 229 _Entity.Number_of_nonpolymer_components . _Entity.Paramagnetic no _Entity.Thiol_state 'not reported' _Entity.Src_method . _Entity.Parent_entity_ID . _Entity.Fragment . _Entity.Mutation . _Entity.EC_number . _Entity.Calc_isoelectric_point . _Entity.Formula_weight . _Entity.Formula_weight_exptl . _Entity.Formula_weight_exptl_meth . _Entity.Details . _Entity.DB_query_date . _Entity.DB_query_revised_last_date . loop_ _Entity_comp_index.ID _Entity_comp_index.Auth_seq_ID _Entity_comp_index.Comp_ID _Entity_comp_index.Comp_label _Entity_comp_index.Entry_ID _Entity_comp_index.Entity_ID 1 . ALA . 26891 1 2 . THR . 26891 1 3 . THR . 26891 1 4 . ASN . 26891 1 5 . THR . 26891 1 6 . VAL . 26891 1 7 . ALA . 26891 1 8 . ALA . 26891 1 9 . TYR . 26891 1 10 . ASN . 26891 1 11 . LEU . 26891 1 12 . THR . 26891 1 13 . TRP . 26891 1 14 . LYS . 26891 1 15 . SER . 26891 1 16 . THR . 26891 1 17 . ASN . 26891 1 18 . PHE . 26891 1 19 . LYS . 26891 1 20 . THR . 26891 1 21 . ILE . 26891 1 22 . LEU . 26891 1 23 . GLU . 26891 1 24 . TRP . 26891 1 25 . GLU . 26891 1 26 . PRO . 26891 1 27 . LYS . 26891 1 28 . PRO . 26891 1 29 . VAL . 26891 1 30 . ASN . 26891 1 31 . GLN . 26891 1 32 . VAL . 26891 1 33 . TYR . 26891 1 34 . THR . 26891 1 35 . VAL . 26891 1 36 . GLN . 26891 1 37 . ILE . 26891 1 38 . SER . 26891 1 39 . THR . 26891 1 40 . LYS . 26891 1 41 . SER . 26891 1 42 . GLY . 26891 1 43 . ASP . 26891 1 44 . TRP . 26891 1 45 . LYS . 26891 1 46 . SER . 26891 1 47 . LYS . 26891 1 48 . CYS . 26891 1 49 . PHE . 26891 1 50 . TYR . 26891 1 51 . THR . 26891 1 52 . THR . 26891 1 53 . ASP . 26891 1 54 . THR . 26891 1 55 . GLU . 26891 1 56 . CYS . 26891 1 57 . ASP . 26891 1 58 . LEU . 26891 1 59 . THR . 26891 1 60 . ASP . 26891 1 61 . GLU . 26891 1 62 . ILE . 26891 1 63 . VAL . 26891 1 64 . LYS . 26891 1 65 . ASP . 26891 1 66 . VAL . 26891 1 67 . LYS . 26891 1 68 . GLN . 26891 1 69 . THR . 26891 1 70 . TYR . 26891 1 71 . LEU . 26891 1 72 . ALA . 26891 1 73 . ARG . 26891 1 74 . VAL . 26891 1 75 . PHE . 26891 1 76 . SER . 26891 1 77 . TYR . 26891 1 78 . PRO . 26891 1 79 . ALA . 26891 1 80 . GLY . 26891 1 81 . ASN . 26891 1 82 . VAL . 26891 1 83 . GLU . 26891 1 84 . SER . 26891 1 85 . THR . 26891 1 86 . GLY . 26891 1 87 . SER . 26891 1 88 . ALA . 26891 1 89 . GLY . 26891 1 90 . GLU . 26891 1 91 . PRO . 26891 1 92 . LEU . 26891 1 93 . TYR . 26891 1 94 . GLU . 26891 1 95 . ASN . 26891 1 96 . SER . 26891 1 97 . PRO . 26891 1 98 . GLU . 26891 1 99 . PHE . 26891 1 100 . THR . 26891 1 101 . PRO . 26891 1 102 . TYR . 26891 1 103 . LEU . 26891 1 104 . GLU . 26891 1 105 . THR . 26891 1 106 . ASN . 26891 1 107 . LEU . 26891 1 108 . GLY . 26891 1 109 . GLN . 26891 1 110 . PRO . 26891 1 111 . THR . 26891 1 112 . ILE . 26891 1 113 . GLN . 26891 1 114 . SER . 26891 1 115 . PHE . 26891 1 116 . GLU . 26891 1 117 . GLN . 26891 1 118 . VAL . 26891 1 119 . GLY . 26891 1 120 . THR . 26891 1 121 . LYS . 26891 1 122 . VAL . 26891 1 123 . ASN . 26891 1 124 . VAL . 26891 1 125 . THR . 26891 1 126 . VAL . 26891 1 127 . GLU . 26891 1 128 . ASP . 26891 1 129 . GLU . 26891 1 130 . ARG . 26891 1 131 . THR . 26891 1 132 . LEU . 26891 1 133 . VAL . 26891 1 134 . ARG . 26891 1 135 . ARG . 26891 1 136 . ASN . 26891 1 137 . ASN . 26891 1 138 . THR . 26891 1 139 . PHE . 26891 1 140 . LEU . 26891 1 141 . SER . 26891 1 142 . LEU . 26891 1 143 . ARG . 26891 1 144 . ASP . 26891 1 145 . VAL . 26891 1 146 . PHE . 26891 1 147 . GLY . 26891 1 148 . LYS . 26891 1 149 . ASP . 26891 1 150 . LEU . 26891 1 151 . ILE . 26891 1 152 . TYR . 26891 1 153 . THR . 26891 1 154 . LEU . 26891 1 155 . TYR . 26891 1 156 . TYR . 26891 1 157 . TRP . 26891 1 158 . LYS . 26891 1 159 . SER . 26891 1 160 . SER . 26891 1 161 . SER . 26891 1 162 . SER . 26891 1 163 . GLY . 26891 1 164 . LYS . 26891 1 165 . LYS . 26891 1 166 . THR . 26891 1 167 . ALA . 26891 1 168 . LYS . 26891 1 169 . THR . 26891 1 170 . ASN . 26891 1 171 . THR . 26891 1 172 . ASN . 26891 1 173 . GLU . 26891 1 174 . PHE . 26891 1 175 . LEU . 26891 1 176 . ILE . 26891 1 177 . ASP . 26891 1 178 . VAL . 26891 1 179 . ASP . 26891 1 180 . LYS . 26891 1 181 . GLY . 26891 1 182 . GLU . 26891 1 183 . ASN . 26891 1 184 . TYR . 26891 1 185 . CYS . 26891 1 186 . PHE . 26891 1 187 . SER . 26891 1 188 . VAL . 26891 1 189 . GLN . 26891 1 190 . ALA . 26891 1 191 . VAL . 26891 1 192 . ILE . 26891 1 193 . PRO . 26891 1 194 . SER . 26891 1 195 . ARG . 26891 1 196 . THR . 26891 1 197 . VAL . 26891 1 198 . ASN . 26891 1 199 . ARG . 26891 1 200 . LYS . 26891 1 201 . SER . 26891 1 202 . THR . 26891 1 203 . ASP . 26891 1 204 . SER . 26891 1 205 . PRO . 26891 1 206 . VAL . 26891 1 207 . GLU . 26891 1 208 . CYS . 26891 1 209 . MET . 26891 1 210 . GLY . 26891 1 211 . GLN . 26891 1 212 . GLU . 26891 1 213 . LYS . 26891 1 214 . GLY . 26891 1 215 . GLU . 26891 1 216 . PHE . 26891 1 217 . ARG . 26891 1 218 . GLU . 26891 1 219 . GLY . 26891 1 220 . GLY . 26891 1 221 . ALA . 26891 1 222 . ALA . 26891 1 223 . GLY . 26891 1 224 . HIS . 26891 1 225 . HIS . 26891 1 226 . HIS . 26891 1 227 . HIS . 26891 1 228 . HIS . 26891 1 229 . HIS . 26891 1 stop_ loop_ _Entity_poly_seq.Hetero _Entity_poly_seq.Mon_ID _Entity_poly_seq.Num _Entity_poly_seq.Comp_index_ID _Entity_poly_seq.Entry_ID _Entity_poly_seq.Entity_ID . ALA 1 1 26891 1 . THR 2 2 26891 1 . THR 3 3 26891 1 . ASN 4 4 26891 1 . THR 5 5 26891 1 . VAL 6 6 26891 1 . ALA 7 7 26891 1 . ALA 8 8 26891 1 . TYR 9 9 26891 1 . ASN 10 10 26891 1 . LEU 11 11 26891 1 . THR 12 12 26891 1 . TRP 13 13 26891 1 . LYS 14 14 26891 1 . SER 15 15 26891 1 . THR 16 16 26891 1 . ASN 17 17 26891 1 . PHE 18 18 26891 1 . LYS 19 19 26891 1 . THR 20 20 26891 1 . ILE 21 21 26891 1 . LEU 22 22 26891 1 . GLU 23 23 26891 1 . TRP 24 24 26891 1 . GLU 25 25 26891 1 . PRO 26 26 26891 1 . LYS 27 27 26891 1 . PRO 28 28 26891 1 . VAL 29 29 26891 1 . ASN 30 30 26891 1 . GLN 31 31 26891 1 . VAL 32 32 26891 1 . TYR 33 33 26891 1 . THR 34 34 26891 1 . VAL 35 35 26891 1 . GLN 36 36 26891 1 . ILE 37 37 26891 1 . SER 38 38 26891 1 . THR 39 39 26891 1 . LYS 40 40 26891 1 . SER 41 41 26891 1 . GLY 42 42 26891 1 . ASP 43 43 26891 1 . TRP 44 44 26891 1 . LYS 45 45 26891 1 . SER 46 46 26891 1 . LYS 47 47 26891 1 . CYS 48 48 26891 1 . PHE 49 49 26891 1 . TYR 50 50 26891 1 . THR 51 51 26891 1 . THR 52 52 26891 1 . ASP 53 53 26891 1 . THR 54 54 26891 1 . GLU 55 55 26891 1 . CYS 56 56 26891 1 . ASP 57 57 26891 1 . LEU 58 58 26891 1 . THR 59 59 26891 1 . ASP 60 60 26891 1 . GLU 61 61 26891 1 . ILE 62 62 26891 1 . VAL 63 63 26891 1 . LYS 64 64 26891 1 . ASP 65 65 26891 1 . VAL 66 66 26891 1 . LYS 67 67 26891 1 . GLN 68 68 26891 1 . THR 69 69 26891 1 . TYR 70 70 26891 1 . LEU 71 71 26891 1 . ALA 72 72 26891 1 . ARG 73 73 26891 1 . VAL 74 74 26891 1 . PHE 75 75 26891 1 . SER 76 76 26891 1 . TYR 77 77 26891 1 . PRO 78 78 26891 1 . ALA 79 79 26891 1 . GLY 80 80 26891 1 . ASN 81 81 26891 1 . VAL 82 82 26891 1 . GLU 83 83 26891 1 . SER 84 84 26891 1 . THR 85 85 26891 1 . GLY 86 86 26891 1 . SER 87 87 26891 1 . ALA 88 88 26891 1 . GLY 89 89 26891 1 . GLU 90 90 26891 1 . PRO 91 91 26891 1 . LEU 92 92 26891 1 . TYR 93 93 26891 1 . GLU 94 94 26891 1 . ASN 95 95 26891 1 . SER 96 96 26891 1 . PRO 97 97 26891 1 . GLU 98 98 26891 1 . PHE 99 99 26891 1 . THR 100 100 26891 1 . PRO 101 101 26891 1 . TYR 102 102 26891 1 . LEU 103 103 26891 1 . GLU 104 104 26891 1 . THR 105 105 26891 1 . ASN 106 106 26891 1 . LEU 107 107 26891 1 . GLY 108 108 26891 1 . GLN 109 109 26891 1 . PRO 110 110 26891 1 . THR 111 111 26891 1 . ILE 112 112 26891 1 . GLN 113 113 26891 1 . SER 114 114 26891 1 . PHE 115 115 26891 1 . GLU 116 116 26891 1 . GLN 117 117 26891 1 . VAL 118 118 26891 1 . GLY 119 119 26891 1 . THR 120 120 26891 1 . LYS 121 121 26891 1 . VAL 122 122 26891 1 . ASN 123 123 26891 1 . VAL 124 124 26891 1 . THR 125 125 26891 1 . VAL 126 126 26891 1 . GLU 127 127 26891 1 . ASP 128 128 26891 1 . GLU 129 129 26891 1 . ARG 130 130 26891 1 . THR 131 131 26891 1 . LEU 132 132 26891 1 . VAL 133 133 26891 1 . ARG 134 134 26891 1 . ARG 135 135 26891 1 . ASN 136 136 26891 1 . ASN 137 137 26891 1 . THR 138 138 26891 1 . PHE 139 139 26891 1 . LEU 140 140 26891 1 . SER 141 141 26891 1 . LEU 142 142 26891 1 . ARG 143 143 26891 1 . ASP 144 144 26891 1 . VAL 145 145 26891 1 . PHE 146 146 26891 1 . GLY 147 147 26891 1 . LYS 148 148 26891 1 . ASP 149 149 26891 1 . LEU 150 150 26891 1 . ILE 151 151 26891 1 . TYR 152 152 26891 1 . THR 153 153 26891 1 . LEU 154 154 26891 1 . TYR 155 155 26891 1 . TYR 156 156 26891 1 . TRP 157 157 26891 1 . LYS 158 158 26891 1 . SER 159 159 26891 1 . SER 160 160 26891 1 . SER 161 161 26891 1 . SER 162 162 26891 1 . GLY 163 163 26891 1 . LYS 164 164 26891 1 . LYS 165 165 26891 1 . THR 166 166 26891 1 . ALA 167 167 26891 1 . LYS 168 168 26891 1 . THR 169 169 26891 1 . ASN 170 170 26891 1 . THR 171 171 26891 1 . ASN 172 172 26891 1 . GLU 173 173 26891 1 . PHE 174 174 26891 1 . LEU 175 175 26891 1 . ILE 176 176 26891 1 . ASP 177 177 26891 1 . VAL 178 178 26891 1 . ASP 179 179 26891 1 . LYS 180 180 26891 1 . GLY 181 181 26891 1 . GLU 182 182 26891 1 . ASN 183 183 26891 1 . TYR 184 184 26891 1 . CYS 185 185 26891 1 . PHE 186 186 26891 1 . SER 187 187 26891 1 . VAL 188 188 26891 1 . GLN 189 189 26891 1 . ALA 190 190 26891 1 . VAL 191 191 26891 1 . ILE 192 192 26891 1 . PRO 193 193 26891 1 . SER 194 194 26891 1 . ARG 195 195 26891 1 . THR 196 196 26891 1 . VAL 197 197 26891 1 . ASN 198 198 26891 1 . ARG 199 199 26891 1 . LYS 200 200 26891 1 . SER 201 201 26891 1 . THR 202 202 26891 1 . ASP 203 203 26891 1 . SER 204 204 26891 1 . PRO 205 205 26891 1 . VAL 206 206 26891 1 . GLU 207 207 26891 1 . CYS 208 208 26891 1 . MET 209 209 26891 1 . GLY 210 210 26891 1 . GLN 211 211 26891 1 . GLU 212 212 26891 1 . LYS 213 213 26891 1 . GLY 214 214 26891 1 . GLU 215 215 26891 1 . PHE 216 216 26891 1 . ARG 217 217 26891 1 . GLU 218 218 26891 1 . GLY 219 219 26891 1 . GLY 220 220 26891 1 . ALA 221 221 26891 1 . ALA 222 222 26891 1 . GLY 223 223 26891 1 . HIS 224 224 26891 1 . HIS 225 225 26891 1 . HIS 226 226 26891 1 . HIS 227 227 26891 1 . HIS 228 228 26891 1 . HIS 229 229 26891 1 stop_ save_ #################### # Natural source # #################### save_natural_source _Entity_natural_src_list.Sf_category natural_source _Entity_natural_src_list.Sf_framecode natural_source _Entity_natural_src_list.Entry_ID 26891 _Entity_natural_src_list.ID 1 loop_ _Entity_natural_src.ID _Entity_natural_src.Entity_ID _Entity_natural_src.Entity_label _Entity_natural_src.Entity_chimera_segment_ID _Entity_natural_src.NCBI_taxonomy_ID _Entity_natural_src.Type _Entity_natural_src.Common _Entity_natural_src.Organism_name_scientific _Entity_natural_src.Organism_name_common _Entity_natural_src.Organism_acronym _Entity_natural_src.ICTVdb_decimal_code _Entity_natural_src.Superkingdom _Entity_natural_src.Kingdom _Entity_natural_src.Genus _Entity_natural_src.Species _Entity_natural_src.Strain _Entity_natural_src.Variant _Entity_natural_src.Organ _Entity_natural_src.Tissue _Entity_natural_src.Tissue_fraction _Entity_natural_src.Cell_line _Entity_natural_src.Cell_type _Entity_natural_src.ATCC_number _Entity_natural_src.Organelle _Entity_natural_src.Secretion _Entity_natural_src.Plasmid _Entity_natural_src.Gene_mnemonic _Entity_natural_src.Details _Entity_natural_src.Entry_ID _Entity_natural_src.Entity_natural_src_list_ID 1 1 $Extracellular_domain_of_tissue_factor . 9606 organism . 'Homo sapiens' Human . . Eukaryota Metazoa Homo sapiens . . . . . . . . . . . . . 26891 1 stop_ save_ ######################### # Experimental source # ######################### save_experimental_source _Entity_experimental_src_list.Sf_category experimental_source _Entity_experimental_src_list.Sf_framecode experimental_source _Entity_experimental_src_list.Entry_ID 26891 _Entity_experimental_src_list.ID 1 loop_ _Entity_experimental_src.ID _Entity_experimental_src.Entity_ID _Entity_experimental_src.Entity_label _Entity_experimental_src.Entity_chimera_segment_ID _Entity_experimental_src.Production_method _Entity_experimental_src.Host_org_scientific_name _Entity_experimental_src.Host_org_name_common _Entity_experimental_src.Host_org_details _Entity_experimental_src.Host_org_NCBI_taxonomy_ID _Entity_experimental_src.Host_org_genus _Entity_experimental_src.Host_org_species _Entity_experimental_src.Host_org_strain _Entity_experimental_src.Host_org_variant _Entity_experimental_src.Host_org_ATCC_number _Entity_experimental_src.Vector_type _Entity_experimental_src.PDBview_host_org_vector_name _Entity_experimental_src.PDBview_plasmid_name _Entity_experimental_src.Vector_name _Entity_experimental_src.Vector_details _Entity_experimental_src.Vendor_name _Entity_experimental_src.Details _Entity_experimental_src.Entry_ID _Entity_experimental_src.Entity_experimental_src_list_ID 1 1 $Extracellular_domain_of_tissue_factor . 'recombinant technology' 'Escherichia coli' . . . Escherichia coli . . . . . . pJH677 . . . 26891 1 stop_ save_ ##################################### # Sample contents and methodology # ##################################### ######################## # Sample description # ######################## save_sample_1 _Sample.Sf_category sample _Sample.Sf_framecode sample_1 _Sample.Entry_ID 26891 _Sample.ID 1 _Sample.Type solution _Sample.Sub_type . _Sample.Details . _Sample.Aggregate_sample_number . _Sample.Solvent_system '90% H2O/10% D2O' _Sample.Preparation_date . _Sample.Preparation_expiration_date . _Sample.Polycrystallization_protocol . _Sample.Single_crystal_protocol . _Sample.Crystal_grow_apparatus . _Sample.Crystal_grow_atmosphere . _Sample.Crystal_grow_details . _Sample.Crystal_grow_method . _Sample.Crystal_grow_method_cit_ID . _Sample.Crystal_grow_pH . _Sample.Crystal_grow_pH_range . _Sample.Crystal_grow_pressure . _Sample.Crystal_grow_pressure_esd . _Sample.Crystal_grow_seeding . _Sample.Crystal_grow_seeding_cit_ID . _Sample.Crystal_grow_temp . _Sample.Crystal_grow_temp_details . _Sample.Crystal_grow_temp_esd . _Sample.Crystal_grow_time . _Sample.Oriented_sample_prep_protocol . _Sample.Lyophilization_cryo_protectant . _Sample.Storage_protocol . loop_ _Sample_component.ID _Sample_component.Mol_common_name _Sample_component.Isotopic_labeling _Sample_component.Assembly_ID _Sample_component.Assembly_label _Sample_component.Entity_ID _Sample_component.Entity_label _Sample_component.Product_ID _Sample_component.Type _Sample_component.Concentration_val _Sample_component.Concentration_val_min _Sample_component.Concentration_val_max _Sample_component.Concentration_val_units _Sample_component.Concentration_val_err _Sample_component.Vendor _Sample_component.Vendor_product_name _Sample_component.Vendor_product_code _Sample_component.Entry_ID _Sample_component.Sample_ID 1 'Extracellular domain of tissue factor' [U-15N] . . 1 $Extracellular_domain_of_tissue_factor . . 100 . . uM . . . . 26891 1 2 'sodium phosphate' 'natural abundance' . . . . . . 50 . . mM . . . . 26891 1 3 'sodium chloride' 'natural abundance' . . . . . . 50 . . mM . . . . 26891 1 4 'sodium azide' 'natural abundance' . . . . . . 0.01 . . % . . . . 26891 1 5 DSS 'natural abundance' . . . . . . 1 . . mM . . . . 26891 1 6 D2O '[U-99% 2H]' . . . . . . 10 . . % . . . . 26891 1 stop_ save_ save_sample_2 _Sample.Sf_category sample _Sample.Sf_framecode sample_2 _Sample.Entry_ID 26891 _Sample.ID 2 _Sample.Type solid _Sample.Sub_type . _Sample.Details . _Sample.Aggregate_sample_number . _Sample.Solvent_system 'PEG precipitated' _Sample.Preparation_date . _Sample.Preparation_expiration_date . _Sample.Polycrystallization_protocol . _Sample.Single_crystal_protocol . _Sample.Crystal_grow_apparatus . _Sample.Crystal_grow_atmosphere . _Sample.Crystal_grow_details . _Sample.Crystal_grow_method . _Sample.Crystal_grow_method_cit_ID . _Sample.Crystal_grow_pH . _Sample.Crystal_grow_pH_range . _Sample.Crystal_grow_pressure . _Sample.Crystal_grow_pressure_esd . _Sample.Crystal_grow_seeding . _Sample.Crystal_grow_seeding_cit_ID . _Sample.Crystal_grow_temp . _Sample.Crystal_grow_temp_details . _Sample.Crystal_grow_temp_esd . _Sample.Crystal_grow_time . _Sample.Oriented_sample_prep_protocol . _Sample.Lyophilization_cryo_protectant . _Sample.Storage_protocol . loop_ _Sample_component.ID _Sample_component.Mol_common_name _Sample_component.Isotopic_labeling _Sample_component.Assembly_ID _Sample_component.Assembly_label _Sample_component.Entity_ID _Sample_component.Entity_label _Sample_component.Product_ID _Sample_component.Type _Sample_component.Concentration_val _Sample_component.Concentration_val_min _Sample_component.Concentration_val_max _Sample_component.Concentration_val_units _Sample_component.Concentration_val_err _Sample_component.Vendor _Sample_component.Vendor_product_name _Sample_component.Vendor_product_code _Sample_component.Entry_ID _Sample_component.Sample_ID 1 'Extracellular domain of tissue factor' '[U-100% 13C; U-100% 15N]' . . 1 $Extracellular_domain_of_tissue_factor . . 45 . . mg/mL . . . . 26891 2 2 'Polyethylene Glycol 3350' 'natural abundance' . . . . . . 20 . . % . . . . 26891 2 3 'sodium phosphate' 'natural abundance' . . . . . . 25 . . mM . . . . 26891 2 4 'sodium chloride' 'natural abundance' . . . . . . 200 . . mM . . . . 26891 2 stop_ save_ save_sample_3 _Sample.Sf_category sample _Sample.Sf_framecode sample_3 _Sample.Entry_ID 26891 _Sample.ID 3 _Sample.Type solid _Sample.Sub_type . _Sample.Details . _Sample.Aggregate_sample_number . _Sample.Solvent_system 'Ammonium sulfate precipitated' _Sample.Preparation_date . _Sample.Preparation_expiration_date . _Sample.Polycrystallization_protocol . _Sample.Single_crystal_protocol . _Sample.Crystal_grow_apparatus . _Sample.Crystal_grow_atmosphere . _Sample.Crystal_grow_details . _Sample.Crystal_grow_method . _Sample.Crystal_grow_method_cit_ID . _Sample.Crystal_grow_pH . _Sample.Crystal_grow_pH_range . _Sample.Crystal_grow_pressure . _Sample.Crystal_grow_pressure_esd . _Sample.Crystal_grow_seeding . _Sample.Crystal_grow_seeding_cit_ID . _Sample.Crystal_grow_temp . _Sample.Crystal_grow_temp_details . _Sample.Crystal_grow_temp_esd . _Sample.Crystal_grow_time . _Sample.Oriented_sample_prep_protocol . _Sample.Lyophilization_cryo_protectant . _Sample.Storage_protocol . loop_ _Sample_component.ID _Sample_component.Mol_common_name _Sample_component.Isotopic_labeling _Sample_component.Assembly_ID _Sample_component.Assembly_label _Sample_component.Entity_ID _Sample_component.Entity_label _Sample_component.Product_ID _Sample_component.Type _Sample_component.Concentration_val _Sample_component.Concentration_val_min _Sample_component.Concentration_val_max _Sample_component.Concentration_val_units _Sample_component.Concentration_val_err _Sample_component.Vendor _Sample_component.Vendor_product_name _Sample_component.Vendor_product_code _Sample_component.Entry_ID _Sample_component.Sample_ID 1 'Extracellular domain of tissue factor' '[U-100% 13C; U-100% 15N]' . . 1 $Extracellular_domain_of_tissue_factor . . 45 . . mg/mL . . . . 26891 3 2 HEPES 'natural abundance' . . . . . . 100 . . mM . . . . 26891 3 3 'sodium chloride' 'natural abundance' . . . . . . 200 . . mM . . . . 26891 3 4 'copper EDTA' 'natural abundance' . . . . . . 5 . . mM . . . . 26891 3 5 'ammonium sulfate' 'natural abundance' . . . . . . 1.8 . . M . . . . 26891 3 stop_ save_ save_sample_4 _Sample.Sf_category sample _Sample.Sf_framecode sample_4 _Sample.Entry_ID 26891 _Sample.ID 4 _Sample.Type solid _Sample.Sub_type . _Sample.Details . _Sample.Aggregate_sample_number . _Sample.Solvent_system 'Ammonium sulfate precipitated' _Sample.Preparation_date . _Sample.Preparation_expiration_date . _Sample.Polycrystallization_protocol . _Sample.Single_crystal_protocol . _Sample.Crystal_grow_apparatus . _Sample.Crystal_grow_atmosphere . _Sample.Crystal_grow_details . _Sample.Crystal_grow_method . _Sample.Crystal_grow_method_cit_ID . _Sample.Crystal_grow_pH . _Sample.Crystal_grow_pH_range . _Sample.Crystal_grow_pressure . _Sample.Crystal_grow_pressure_esd . _Sample.Crystal_grow_seeding . _Sample.Crystal_grow_seeding_cit_ID . _Sample.Crystal_grow_temp . _Sample.Crystal_grow_temp_details . _Sample.Crystal_grow_temp_esd . _Sample.Crystal_grow_time . _Sample.Oriented_sample_prep_protocol . _Sample.Lyophilization_cryo_protectant . _Sample.Storage_protocol . loop_ _Sample_component.ID _Sample_component.Mol_common_name _Sample_component.Isotopic_labeling _Sample_component.Assembly_ID _Sample_component.Assembly_label _Sample_component.Entity_ID _Sample_component.Entity_label _Sample_component.Product_ID _Sample_component.Type _Sample_component.Concentration_val _Sample_component.Concentration_val_min _Sample_component.Concentration_val_max _Sample_component.Concentration_val_units _Sample_component.Concentration_val_err _Sample_component.Vendor _Sample_component.Vendor_product_name _Sample_component.Vendor_product_code _Sample_component.Entry_ID _Sample_component.Sample_ID 1 'Extracellular domain of tissue factor' '[U-100% 2-gly 13C; U-100% 15N; U-80% 2H]' . . 1 $Extracellular_domain_of_tissue_factor . . 45 . . mg/mL . . . . 26891 4 2 HEPES 'natural abundance' . . . . . . 100 . . mM . . . . 26891 4 3 'sodium chloride' 'natural abundance' . . . . . . 200 . . mM . . . . 26891 4 4 'copper EDTA' 'natural abundance' . . . . . . 5 . . mM . . . . 26891 4 5 'ammonium sulfate' 'natural abundance' . . . . . . 1.8 . . M . . . . 26891 4 stop_ save_ ####################### # Sample conditions # ####################### save_sample_conditions_1 _Sample_condition_list.Sf_category sample_conditions _Sample_condition_list.Sf_framecode sample_conditions_1 _Sample_condition_list.Entry_ID 26891 _Sample_condition_list.ID 1 _Sample_condition_list.Details . loop_ _Sample_condition_variable.Type _Sample_condition_variable.Val _Sample_condition_variable.Val_err _Sample_condition_variable.Val_units _Sample_condition_variable.Entry_ID _Sample_condition_variable.Sample_condition_list_ID 'ionic strength' 90 . mM 26891 1 pH 6.5 . pH 26891 1 pressure 1 . atm 26891 1 temperature 273 . K 26891 1 stop_ save_ save_sample_conditions_2 _Sample_condition_list.Sf_category sample_conditions _Sample_condition_list.Sf_framecode sample_conditions_2 _Sample_condition_list.Entry_ID 26891 _Sample_condition_list.ID 2 _Sample_condition_list.Details . loop_ _Sample_condition_variable.Type _Sample_condition_variable.Val _Sample_condition_variable.Val_err _Sample_condition_variable.Val_units _Sample_condition_variable.Entry_ID _Sample_condition_variable.Sample_condition_list_ID pH 7.5 . pH 26891 2 temperature 273 . K 26891 2 stop_ save_ save_sample_conditions_3 _Sample_condition_list.Sf_category sample_conditions _Sample_condition_list.Sf_framecode sample_conditions_3 _Sample_condition_list.Entry_ID 26891 _Sample_condition_list.ID 3 _Sample_condition_list.Details . loop_ _Sample_condition_variable.Type _Sample_condition_variable.Val _Sample_condition_variable.Val_err _Sample_condition_variable.Val_units _Sample_condition_variable.Entry_ID _Sample_condition_variable.Sample_condition_list_ID pH 7.5 . pH 26891 3 temperature 273 . K 26891 3 stop_ save_ ############################ # Computer software used # ############################ save_VNMRJ _Software.Sf_category software _Software.Sf_framecode VNMRJ _Software.Entry_ID 26891 _Software.ID 1 _Software.Name VNMRJ _Software.Version . _Software.Details . loop_ _Vendor.Name _Vendor.Address _Vendor.Electronic_address _Vendor.Entry_ID _Vendor.Software_ID Varian . . 26891 1 stop_ loop_ _Task.Task _Task.Entry_ID _Task.Software_ID collection 26891 1 stop_ save_ save_SPARKY _Software.Sf_category software _Software.Sf_framecode SPARKY _Software.Entry_ID 26891 _Software.ID 2 _Software.Name SPARKY _Software.Version . _Software.Details . loop_ _Vendor.Name _Vendor.Address _Vendor.Electronic_address _Vendor.Entry_ID _Vendor.Software_ID Goddard . . 26891 2 stop_ loop_ _Task.Task _Task.Entry_ID _Task.Software_ID 'peak picking' 26891 2 stop_ save_ ######################### # Experimental detail # ######################### ################################## # NMR Spectrometer definitions # ################################## save_spectrometer_1 _NMR_spectrometer.Sf_category NMR_spectrometer _NMR_spectrometer.Sf_framecode spectrometer_1 _NMR_spectrometer.Entry_ID 26891 _NMR_spectrometer.ID 1 _NMR_spectrometer.Details . _NMR_spectrometer.Manufacturer Varian _NMR_spectrometer.Model VNMRS _NMR_spectrometer.Serial_number . _NMR_spectrometer.Field_strength 750 save_ save_spectrometer_2 _NMR_spectrometer.Sf_category NMR_spectrometer _NMR_spectrometer.Sf_framecode spectrometer_2 _NMR_spectrometer.Entry_ID 26891 _NMR_spectrometer.ID 2 _NMR_spectrometer.Details . _NMR_spectrometer.Manufacturer Varian _NMR_spectrometer.Model VNMRS _NMR_spectrometer.Serial_number . _NMR_spectrometer.Field_strength 500 save_ save_NMR_spectrometer_list _NMR_spectrometer_list.Sf_category NMR_spectrometer_list _NMR_spectrometer_list.Sf_framecode NMR_spectrometer_list _NMR_spectrometer_list.Entry_ID 26891 _NMR_spectrometer_list.ID 1 loop_ _NMR_spectrometer_view.ID _NMR_spectrometer_view.Name _NMR_spectrometer_view.Manufacturer _NMR_spectrometer_view.Model _NMR_spectrometer_view.Serial_number _NMR_spectrometer_view.Field_strength _NMR_spectrometer_view.Details _NMR_spectrometer_view.Citation_ID _NMR_spectrometer_view.Citation_label _NMR_spectrometer_view.Entry_ID _NMR_spectrometer_view.NMR_spectrometer_list_ID 1 spectrometer_1 Varian VNMRS . 750 . . . 26891 1 2 spectrometer_2 Varian VNMRS . 500 . . . 26891 1 stop_ save_ ############################# # NMR applied experiments # ############################# save_experiment_list _Experiment_list.Sf_category experiment_list _Experiment_list.Sf_framecode experiment_list _Experiment_list.Entry_ID 26891 _Experiment_list.ID 1 _Experiment_list.Details . loop_ _Experiment.ID _Experiment.Name _Experiment.Raw_data_flag _Experiment.NMR_spec_expt_ID _Experiment.NMR_spec_expt_label _Experiment.MS_expt_ID _Experiment.MS_expt_label _Experiment.SAXS_expt_ID _Experiment.SAXS_expt_label _Experiment.FRET_expt_ID _Experiment.FRET_expt_label _Experiment.EMR_expt_ID _Experiment.EMR_expt_label _Experiment.Sample_ID _Experiment.Sample_label _Experiment.Sample_state _Experiment.Sample_volume _Experiment.Sample_volume_units _Experiment.Sample_condition_list_ID _Experiment.Sample_condition_list_label _Experiment.Sample_spinning_rate _Experiment.Sample_angle _Experiment.NMR_tube_type _Experiment.NMR_spectrometer_ID _Experiment.NMR_spectrometer_label _Experiment.NMR_spectrometer_probe_ID _Experiment.NMR_spectrometer_probe_label _Experiment.NMR_spectral_processing_ID _Experiment.NMR_spectral_processing_label _Experiment.Mass_spectrometer_ID _Experiment.Mass_spectrometer_label _Experiment.Xray_instrument_ID _Experiment.Xray_instrument_label _Experiment.Fluorescence_instrument_ID _Experiment.Fluorescence_instrument_label _Experiment.EMR_instrument_ID _Experiment.EMR_instrument_label _Experiment.Chromatographic_system_ID _Experiment.Chromatographic_system_label _Experiment.Chromatographic_column_ID _Experiment.Chromatographic_column_label _Experiment.Entry_ID _Experiment.Experiment_list_ID 1 '2D 1H-15N HSQC' yes 1 $NMR_spectrometer_expt . . . . . . . . 1 $sample_1 isotropic . . 1 $sample_conditions_1 . . . . . . . . . . . . . . . . . . . . . 26891 1 2 '2D 13C-13C DARR' yes 1 $NMR_spectrometer_expt . . . . . . . . 2 $sample_2 anisotropic . . 2 $sample_conditions_2 . . . . . . . . . . . . . . . . . . . . . 26891 1 3 '2D 13C-13C DARR' yes 1 $NMR_spectrometer_expt . . . . . . . . 3 $sample_3 anisotropic . . 3 $sample_conditions_3 . . . . . . . . . . . . . . . . . . . . . 26891 1 4 '2D 15N-13CA' yes 1 $NMR_spectrometer_expt . . . . . . . . 3 $sample_3 anisotropic . . 3 $sample_conditions_3 . . . . . . . . . . . . . . . . . . . . . 26891 1 5 '2D 15N-13CA' yes 1 $NMR_spectrometer_expt . . . . . . . . 4 $sample_4 anisotropic . . 3 $sample_conditions_3 . . . . . . . . . . . . . . . . . . . . . 26891 1 stop_ save_ save_NMR_spectrometer_expt _NMR_spec_expt.Sf_category NMR_spectrometer_expt _NMR_spec_expt.Sf_framecode NMR_spectrometer_expt _NMR_spec_expt.Entry_ID 26891 _NMR_spec_expt.ID 1 _NMR_spec_expt.Name . _NMR_spec_expt.Type . _NMR_spec_expt.Sample_volume . _NMR_spec_expt.Sample_volume_units . _NMR_spec_expt.NMR_tube_type . _NMR_spec_expt.Sample_spinning_rate . _NMR_spec_expt.Sample_angle . _NMR_spec_expt.NMR_spectrometer_ID . _NMR_spec_expt.NMR_spectrometer_label . _NMR_spec_expt.NMR_spectrometer_probe_ID . _NMR_spec_expt.NMR_spectrometer_probe_label . _NMR_spec_expt.Carrier_freq_switch_time . _NMR_spec_expt.Software_ID . _NMR_spec_expt.Software_label . _NMR_spec_expt.Method_ID . _NMR_spec_expt.Method_label . _NMR_spec_expt.Pulse_seq_accession_BMRB_code . _NMR_spec_expt.Details . loop_ _NMR_experiment_file.Name _NMR_experiment_file.Type _NMR_experiment_file.Directory_path _NMR_experiment_file.Byte_order _NMR_experiment_file.Bytes_per_data_point _NMR_experiment_file.File_header_size _NMR_experiment_file.Record_header_size _NMR_experiment_file.Record_trailer_size _NMR_experiment_file.Compression_algorithm _NMR_experiment_file.Details _NMR_experiment_file.Entry_ID _NMR_experiment_file.NMR_spec_expt_ID '1H-15N HSQC' 'Time-domain (raw spectral data)' . . . . . . . . 26891 1 '2D 13C-13C DARR' 'Time-domain (raw spectral data)' . . . . . . . 'PEG-precipitated sTF' 26891 1 '2D 13C-13C DARR' 'Time-domain (raw spectral data)' . . . . . . . 'Ammonium sulfate-precipitated sTF' 26891 1 '2D 15N,2-13CA' 'NMR experiment directory' . . . . . . . '2-13C glycerol ammonium sulfate-precipitated sTF' 26891 1 '2D 15N-13CA' 'Time-domain (raw spectral data)' . . . . . . . 'Ammonium sulfate-precipitated sTF' 26891 1 stop_ save_ ######################### # Spectral peak lists # ######################### save_1H-15_HSQC _Spectral_peak_list.Sf_category spectral_peak_list _Spectral_peak_list.Sf_framecode 1H-15_HSQC _Spectral_peak_list.Entry_ID 26891 _Spectral_peak_list.ID 1 _Spectral_peak_list.Sample_ID 1 _Spectral_peak_list.Sample_label $sample_1 _Spectral_peak_list.Sample_condition_list_ID 1 _Spectral_peak_list.Sample_condition_list_label $sample_conditions_1 _Spectral_peak_list.Experiment_ID 1 _Spectral_peak_list.Experiment_name '2D 1H-15N HSQC' _Spectral_peak_list.Number_of_spectral_dimensions 2 _Spectral_peak_list.Details . _Spectral_peak_list.Text_data_format text _Spectral_peak_list.Text_data ; Assignment w1 w2 ?-? 104.981 8.02 ?-? 130.648 9.207 ?-? 130.348 8.736 ?-? 129.86 10.116 ?-? 129.699 10.094 ?-? 129.561 8.75 ?-? 129.357 8.917 ?-? 129.171 9.564 ?-? 128.858 9.068 ?-? 128.775 9.271 ?-? 128.761 9.271 ?-? 128.711 8.821 ?-? 128.636 10.025 ?-? 128.462 9.415 ?-? 128.445 9.422 ?-? 128.414 8.104 ?-? 128.334 8.9 ?-? 128.316 8.616 ?-? 128.123 8.816 ?-? 127.904 8.333 ?-? 127.665 8.747 ?-? 127.613 9.18 ?-? 127.348 9.944 ?-? 127.221 9.174 ?-? 127.161 9.334 ?-? 127.08 9.111 ?-? 127.049 8.603 ?-? 126.769 7.654 ?-? 126.683 8.419 ?-? 126.64 8.696 ?-? 126.553 8.318 ?-? 126.479 8.309 ?-? 126.419 9.098 ?-? 126.193 8.398 ?-? 126.198 8.304 ?-? 126.135 8.968 ?-? 126.104 8.792 ?-? 126.052 8.362 ?-? 125.952 9.434 ?-? 125.994 9.444 ?-? 125.987 8.652 ?-? 125.835 9.513 ?-? 125.761 9.05 ?-? 125.509 8.053 ?-? 125.334 8.511 ?-? 124.755 8.724 ?-? 124.728 7.635 ?-? 124.616 8.505 ?-? 124.601 8.462 ?-? 124.247 8.773 ?-? 124.241 8.825 ?-? 124.212 8.714 ?-? 123.962 8.23 ?-? 123.608 9.213 ?-? 123.629 8.926 ?-? 123.576 9.326 ?-? 123.546 9.259 ?-? 123.544 8.462 ?-? 123.545 7.653 ?-? 123.486 8.929 ?-? 123.422 8.77 ?-? 123.521 8.17 ?-? 123.463 8.81 ?-? 123.426 8.12 ?-? 123.456 8.602 ?-? 123.367 8.567 ?-? 123.367 5.888 ?-? 123.335 9.205 ?-? 123.239 8.811 ?-? 123.122 8.823 ?-? 123.192 8.82 ?-? 123.097 7.934 ?-? 123.057 10.077 ?-? 123.052 8.251 ?-? 123.028 8.621 ?-? 122.979 8.8 ?-? 122.962 8.824 ?-? 122.956 8.76 ?-? 122.944 8.506 ?-? 122.967 8.397 ?-? 122.933 7.778 ?-? 122.871 8.253 ?-? 122.888 8.425 ?-? 122.789 8.699 ?-? 122.745 8.864 ?-? 122.673 8.541 ?-? 122.623 8.712 ?-? 122.643 8.661 ?-? 122.533 8.615 ?-? 122.625 8.245 ?-? 122.607 8.813 ?-? 122.659 8.767 ?-? 122.603 8.505 ?-? 122.512 9.041 ?-? 122.538 9.002 ?-? 122.445 8.146 ?-? 122.353 7.429 ?-? 122.352 8.492 ?-? 122.308 8.419 ?-? 122.281 8.533 ?-? 122.281 8.198 ?-? 122.262 8.246 ?-? 122.076 8.209 ?-? 121.919 9.101 ?-? 121.924 8.29 ?-? 121.905 8.817 ?-? 121.805 8.248 ?-? 121.662 8.339 ?-? 121.767 8.237 ?-? 121.73 8.168 ?-? 121.655 8.041 ?-? 121.441 9.189 ?-? 121.435 9.09 ?-? 121.443 8.421 ?-? 121.444 8.329 ?-? 121.376 9.036 ?-? 121.319 8.69 ?-? 121.336 8.639 ?-? 121.305 8.609 ?-? 121.181 8.886 ?-? 121.206 8.565 ?-? 121.189 8.534 ?-? 121.125 8.702 ?-? 121.045 8.604 ?-? 121.056 8.193 ?-? 121.019 8.882 ?-? 121.01 8.766 ?-? 120.992 8.15 ?-? 120.998 8.766 ?-? 120.99 8.663 ?-? 120.932 8.556 ?-? 120.962 8.107 ?-? 120.898 8.466 ?-? 120.842 8.62 ?-? 120.75 9.226 ?-? 120.753 8.768 ?-? 120.618 8.716 ?-? 120.686 8.616 ?-? 120.636 8.573 ?-? 120.617 8.251 ?-? 120.683 8.193 ?-? 120.715 8.327 ?-? 120.417 8.71 ?-? 120.079 8.902 ?-? 120.103 7.822 ?-? 120.063 8.196 ?-? 119.926 8.814 ?-? 119.935 8.195 ?-? 119.911 6.825 ?-? 119.919 8.808 ?-? 119.9 8.565 ?-? 119.634 9.099 ?-? 119.55 8.395 ?-? 119.418 9.384 ?-? 119.33 8.041 ?-? 119.333 7.945 ?-? 119.286 8.096 ?-? 119.266 8.922 ?-? 119.158 9.259 ?-? 119.107 8.811 ?-? 119.072 8.097 ?-? 119.034 8.312 ?-? 118.945 8.259 ?-? 119.026 8.244 ?-? 119.049 8.045 ?-? 119.048 8.238 ?-? 119.006 8.196 ?-? 119.03 6.958 ?-? 118.938 8.171 ?-? 118.878 9.477 ?-? 118.866 8.573 ?-? 118.841 8.593 ?-? 118.842 8.082 ?-? 118.816 8.094 ?-? 118.758 9.034 ?-? 118.699 9.252 ?-? 118.67 8.165 ?-? 118.672 8.062 ?-? 118.613 8.248 ?-? 118.488 7.648 ?-? 118.43 7.946 ?-? 118.072 7.367 ?-? 117.886 9.066 ?-? 117.915 8.693 ?-? 117.879 9.054 ?-? 117.825 9.588 ?-? 117.637 8.173 ?-? 117.585 9.401 ?-? 117.609 8.278 ?-? 117.573 9.299 ?-? 117.391 8.402 ?-? 117.364 8.925 ?-? 117.362 8.441 ?-? 117.153 7.468 ?-? 116.77 9.186 ?-? 116.763 7.904 ?-? 116.741 8.451 ?-? 116.62 8.515 ?-? 116.505 8.948 ?-? 116.455 8.198 ?-? 116.203 8.245 ?-? 115.979 7.855 ?-? 115.832 7.464 ?-? 115.782 8.753 ?-? 115.819 8.178 ?-? 115.618 7.629 ?-? 115.531 8.527 ?-? 115.414 8.308 ?-? 115.332 8.403 ?-? 115.3 7.898 ?-? 115.13 8.429 ?-? 115.072 8.841 ?-? 114.954 8.238 ?-? 114.955 8.135 ?-? 114.875 7.651 ?-? 114.658 8.283 ?-? 114.658 8.21 ?-? 114.714 8.229 ?-? 114.514 7.699 ?-? 114.406 8.29 ?-? 114.429 8.227 ?-? 114.141 9.575 ?-? 113.899 8.567 ?-? 113.893 8.61 ?-? 113.881 7.86 ?-? 113.816 8.833 ?-? 113.503 8.579 ?-? 113.328 8.013 ?-? 113.305 7.541 ?-? 113.306 6.874 ?-? 113.13 7.952 ?-? 113.134 7.609 ?-? 113.114 6.973 ?-? 113.129 6.907 ?-? 113.132 6.761 ?-? 113.038 7.622 ?-? 113.056 6.905 ?-? 112.851 6.173 ?-? 112.786 7.613 ?-? 112.803 6.59 ?-? 112.767 6.609 ?-? 112.637 7.951 ?-? 112.636 7.608 ?-? 112.639 6.948 ?-? 112.612 8.654 ?-? 112.629 7.568 ?-? 112.629 6.88 ?-? 112.507 9.097 ?-? 112.383 7.621 ?-? 112.37 7.567 ?-? 112.37 6.949 ?-? 112.3 8.011 ?-? 112.306 7.49 ?-? 112.303 7.071 ?-? 112.305 6.881 ?-? 112.26 8.818 ?-? 112.244 8.735 ?-? 112.228 7.171 ?-? 112.245 6.949 ?-? 112.18 6.73 ?-? 112.177 7.564 ?-? 112.152 6.951 ?-? 112.082 7.154 ?-? 112.097 6.881 ?-? 112.061 8.403 ?-? 112.059 7.491 ?-? 112.064 6.907 ?-? 112.061 6.84 ?-? 112.031 7.428 ?-? 111.91 6.882 ?-? 111.888 8.013 ?-? 111.885 7.568 ?-? 111.821 6.952 ?-? 111.796 6.882 ?-? 111.799 7.492 ?-? 111.732 7.406 ?-? 111.732 7.089 ?-? 111.71 7.566 ?-? 111.67 7.622 ?-? 111.67 6.793 ?-? 111.664 6.733 ?-? 111.625 7.874 ?-? 111.656 7.155 ?-? 111.632 6.915 ?-? 111.627 6.856 ?-? 111.543 7.429 ?-? 111.459 7.72 ?-? 111.462 7.05 ?-? 111.404 6.837 ?-? 111.216 7.625 ?-? 111.184 6.792 ?-? 111.18 7.876 ?-? 111.178 7.095 ?-? 111.185 6.857 ?-? 111.111 7.876 ?-? 111.103 6.861 ?-? 111.033 6.808 ?-? 111.015 7.815 ?-? 110.992 7.721 ?-? 110.964 8.721 ?-? 111.026 8.427 ?-? 110.945 8.372 ?-? 110.926 8.211 ?-? 110.884 7.05 ?-? 110.832 6.954 ?-? 110.818 6.81 ?-? 110.641 8.639 ?-? 110.489 8.485 ?-? 110.324 6.957 ?-? 110.315 6.81 ?-? 110.208 8.055 ?-? 110.076 7.483 ?-? 109.992 8.453 ?-? 109.829 7.253 ?-? 109.828 6.866 ?-? 109.356 7.253 ?-? 109.369 6.868 ?-? 109.287 6.867 ?-? 109.268 8.28 ?-? 109.173 8.719 ?-? 109.113 6.866 ?-? 108.965 8.279 ?-? 108.896 7.655 ?-? 108.836 8.264 ?-? 108.414 7.964 ?-? 107.974 8.117 ?-? 107.739 8.182 ?-? 107.599 7.364 ?-? 107.612 6.725 ?-? 107.56 7.355 ?-? 107.557 6.738 ?-? 107.499 8.363 ?-? 107.484 8.2 ?-? 105.047 7.699 ?-? 131.923 9.207 ; loop_ _Spectral_dim.ID _Spectral_dim.Atom_type _Spectral_dim.Atom_isotope_number _Spectral_dim.Spectral_region _Spectral_dim.Magnetization_linkage_ID _Spectral_dim.Under_sampling_type _Spectral_dim.Sweep_width _Spectral_dim.Sweep_width_units _Spectral_dim.Center_frequency_offset _Spectral_dim.Encoding_code _Spectral_dim.Encoded_reduced_dimension_ID _Spectral_dim.Entry_ID _Spectral_dim.Spectral_peak_list_ID 2 H-N 15 HN . . 12019 Hz . . . 26891 1 stop_ save_ save_13C-13C_2D_DARR _Spectral_peak_list.Sf_category spectral_peak_list _Spectral_peak_list.Sf_framecode 13C-13C_2D_DARR _Spectral_peak_list.Entry_ID 26891 _Spectral_peak_list.ID 2 _Spectral_peak_list.Sample_ID 2 _Spectral_peak_list.Sample_label $sample_2 _Spectral_peak_list.Sample_condition_list_ID 2 _Spectral_peak_list.Sample_condition_list_label $sample_conditions_2 _Spectral_peak_list.Experiment_ID 2 _Spectral_peak_list.Experiment_name '2D 13C-13C DARR' _Spectral_peak_list.Number_of_spectral_dimensions 2 _Spectral_peak_list.Details . _Spectral_peak_list.Text_data_format text _Spectral_peak_list.Text_data ; Assignment w1 w2 ?-? 39.53 133.232 ?-? 139.577 115.146 ?-? 118.019 133.376 ?-? 133.364 117.892 ?-? 19.112 175.967 ?-? 18.842 174.651 ?-? 18.293 175.454 ?-? 18.097 175.015 ?-? 17.605 175.534 ?-? 17.28 174.835 ?-? 16.975 178.196 ?-? 15.691 172.498 ?-? 43.993 130.483 ?-? 43.969 128.888 ?-? 43.77 131.617 ?-? 43.622 130.866 ?-? 43.45 131.867 ?-? 43.41 130.334 ?-? 43.201 131.276 ?-? 43.013 130.994 ?-? 42.946 129.972 ?-? 42.928 131.777 ?-? 42.702 129.09 ?-? 42.4 130.669 ?-? 42.401 128.994 ?-? 42.301 129.886 ?-? 42.097 132.18 ?-? 42.058 131.34 ?-? 41.97 132.085 ?-? 41.797 130.136 ?-? 41.747 131.945 ?-? 41.577 131.492 ?-? 41.543 129.807 ?-? 41.498 129.357 ?-? 41.262 131.177 ?-? 41.179 131.868 ?-? 41.093 130.864 ?-? 41.021 131.339 ?-? 40.911 133.017 ?-? 40.935 130.035 ?-? 40.859 131.174 ?-? 40.853 129.503 ?-? 40.441 131.381 ?-? 40.371 131.918 ?-? 40.302 128.587 ?-? 115.212 139.495 ?-? 70.926 172.035 ?-? 172.31 71.092 ?-? 173.085 73.275 ?-? 73.41 173.09 ?-? 173.928 70.651 ?-? 174.448 68.614 ?-? 68.643 174.476 ?-? 69.888 175.597 ?-? 67.19 174.975 ?-? 174.975 67.151 ?-? 69.474 174.687 ?-? 175.496 69.754 ?-? 171.773 63.289 ?-? 179.255 62.899 ?-? 179.395 57.352 ?-? 180.418 54.653 ?-? 170.908 55.172 ?-? 183.756 38.356 ?-? 184.145 34.784 ?-? 184.45 36.03 ?-? 183.564 36.535 ?-? 183.271 36.916 ?-? 180.581 33.46 ?-? 176.767 26.143 ?-? 176.008 19.019 ?-? 172.163 21.78 ?-? 180.966 35.221 ?-? 182.8 35.866 ?-? 65.394 178.097 ?-? 63.253 171.748 ?-? 55.212 170.954 ?-? 62.96 179.32 ?-? 54.572 180.405 ?-? 57.336 179.452 ?-? 177.982 62.092 ?-? 62.245 178.415 ?-? 21.684 172.322 ?-? 18.942 174.289 ?-? 33.5 180.688 ?-? 38.199 183.785 ?-? 35.357 181.074 ?-? 34.836 184.185 ?-? 35.863 184.347 ?-? 35.887 182.66 ?-? 34.652 182.662 ?-? 33.211 184.181 ?-? 73.274 61.145 ?-? 73.291 22.746 ?-? 72.986 59.244 ?-? 72.909 22.044 ?-? 72.896 60.593 ?-? 72.769 21.024 ?-? 72.713 71.438 ?-? 72.728 59.684 ?-? 72.588 61.228 ?-? 72.541 72.545 ?-? 72.391 22.122 ?-? 72.361 63.668 ?-? 72.278 70.968 ?-? 72.26 21.918 ?-? 72.228 62.027 ?-? 71.492 61.978 ?-? 71.472 20.944 ?-? 71.377 71.38 ?-? 71.36 59.616 ?-? 71.113 71.114 ?-? 71.05 60.96 ?-? 71.088 59.833 ?-? 70.904 70.904 ?-? 70.887 19.357 ?-? 70.845 59.121 ?-? 70.817 72.207 ?-? 70.75 61.411 ?-? 70.703 21.528 ?-? 70.646 61.559 ?-? 70.543 61.631 ?-? 70.445 71.713 ?-? 70.439 61.794 ?-? 70.247 22.557 ?-? 70.176 71.36 ?-? 69.902 20.929 ?-? 69.871 61.976 ?-? 69.81 20.837 ?-? 69.729 69.733 ?-? 69.706 20.714 ?-? 69.573 69.586 ?-? 69.578 20.547 ?-? 69.523 22.354 ?-? 69.375 63.246 ?-? 69.333 67.924 ?-? 69.323 61.636 ?-? 69.305 22.519 ?-? 69.177 69.189 ?-? 69.121 61.104 ?-? 68.951 58.679 ?-? 68.95 20.799 ?-? 68.9 68.899 ?-? 68.805 18.037 ?-? 68.794 64.482 ?-? 68.744 59.908 ?-? 68.664 21.604 ?-? 68.2 61.629 ?-? 67.997 70.008 ?-? 67.998 69.381 ?-? 67.982 67.975 ?-? 67.969 21.806 ?-? 67.879 61.4 ?-? 67.323 67.285 ?-? 67.171 57.825 ?-? 67.142 66.222 ?-? 66.102 23.094 ?-? 66.068 32.425 ?-? 65.868 65.889 ?-? 65.91 58.326 ?-? 65.798 21.918 ?-? 65.764 20.973 ?-? 65.411 28.288 ?-? 65.386 31.576 ?-? 65.299 66.339 ?-? 65.086 65.073 ?-? 65.089 57.177 ?-? 64.817 56.29 ?-? 64.773 59.333 ?-? 64.679 59.43 ?-? 64.634 55.534 ?-? 64.581 59.503 ?-? 64.543 68.753 ?-? 64.559 64.569 ?-? 64.564 59.063 ?-? 64.51 18.034 ?-? 64.473 61.309 ?-? 64.421 32.286 ?-? 64.263 65.82 ?-? 64.054 59.055 ?-? 64.085 58.605 ?-? 63.922 30.82 ?-? 63.868 59.968 ?-? 63.789 30.662 ?-? 63.687 17.613 ?-? 63.658 31.159 ?-? 63.659 22.152 ?-? 63.61 72.345 ?-? 63.517 32.07 ?-? 63.527 22.912 ?-? 63.478 30.834 ?-? 63.481 28.419 ?-? 63.307 57.778 ?-? 63.296 27.795 ?-? 63.316 22.51 ?-? 63.239 50.785 ?-? 63.269 31.654 ?-? 63.218 63.219 ?-? 63.198 61.012 ?-? 63.211 59.249 ?-? 63.218 38.022 ?-? 63.147 59.903 ?-? 63.119 69.476 ?-? 63.113 29.453 ?-? 63.081 17.139 ?-? 63.046 65.221 ?-? 63.025 32.501 ?-? 62.947 28.406 ?-? 62.917 37.832 ?-? 62.6 60.681 ?-? 62.58 59.463 ?-? 62.507 22.734 ?-? 62.413 33.519 ?-? 62.455 31.907 ?-? 62.436 28.342 ?-? 62.439 23.224 ?-? 62.415 21.842 ?-? 62.41 64.3 ?-? 62.28 59.052 ?-? 62.262 30.415 ?-? 62.141 57.897 ?-? 62.136 54.552 ?-? 62.122 38.035 ?-? 62.056 64.101 ?-? 61.968 72.191 ?-? 61.94 71.486 ?-? 61.895 69.881 ?-? 61.919 61.899 ?-? 61.915 22.605 ?-? 61.862 57.616 ?-? 61.807 61.797 ?-? 61.762 33.725 ?-? 61.736 21.715 ?-? 61.714 20.898 ?-? 61.588 67.981 ?-? 61.591 19.906 ?-? 61.508 70.674 ?-? 61.446 59.656 ?-? 61.461 57.823 ?-? 61.366 63.707 ?-? 61.292 72.557 ?-? 61.283 59.002 ?-? 61.193 33.167 ?-? 61.083 61.087 ?-? 61.101 33.819 ?-? 60.998 60.99 ?-? 60.947 58.138 ?-? 60.964 33.003 ?-? 60.944 20.09 ?-? 60.837 71.111 ?-? 60.731 70.307 ?-? 60.749 69.286 ?-? 60.742 63.253 ?-? 60.731 60.744 ?-? 60.752 58.835 ?-? 60.75 57.84 ?-? 60.747 23.469 ?-? 60.699 62.658 ?-? 60.717 33.602 ?-? 60.689 22.148 ?-? 60.669 63.187 ?-? 60.684 60.683 ?-? 60.643 21.588 ?-? 60.6 72.75 ?-? 60.572 62.853 ?-? 60.598 34.733 ?-? 60.54 21.168 ?-? 60.519 20.601 ?-? 60.479 72.949 ?-? 60.358 63.537 ?-? 60.307 58.042 ?-? 60.149 59.027 ?-? 60.134 42.05 ?-? 60.074 62.103 ?-? 60.052 60.063 ?-? 60.079 35.794 ?-? 60.05 21.542 ?-? 59.992 59.993 ?-? 59.892 68.635 ?-? 59.806 63.102 ?-? 59.803 19.146 ?-? 59.661 61.195 ?-? 59.618 71.198 ?-? 59.577 64.549 ?-? 59.584 57.653 ?-? 59.489 62.772 ?-? 59.444 35.128 ?-? 59.262 72.994 ?-? 59.286 32.381 ?-? 59.234 70.927 ?-? 59.19 59.182 ?-? 59.189 36.618 ?-? 59.182 25.924 ?-? 59.176 19.423 ?-? 59.167 63.235 ?-? 59.158 54.969 ?-? 59.117 19.355 ?-? 59.013 64.052 ?-? 59.026 59.023 ?-? 58.982 62.637 ?-? 58.957 63.99 ?-? 58.882 60.548 ?-? 58.89 19.001 ?-? 58.837 64.441 ?-? 58.852 26.973 ?-? 58.799 43.519 ?-? 58.812 28.733 ?-? 58.747 18.064 ?-? 58.718 41.824 ?-? 58.667 58.674 ?-? 58.622 56.655 ?-? 58.622 36.305 ?-? 58.643 27.318 ?-? 58.591 69.015 ?-? 58.603 60.151 ?-? 58.553 53.32 ?-? 58.56 43.183 ?-? 58.542 20.848 ?-? 58.523 66.446 ?-? 58.487 35.898 ?-? 58.439 41.01 ?-? 58.384 54.354 ?-? 58.379 21.962 ?-? 58.311 19.009 ?-? 58.288 65.91 ?-? 58.17 58.159 ?-? 58.162 54.464 ?-? 58.093 64.569 ?-? 58.073 60.517 ?-? 58.091 55.033 ?-? 57.981 27.507 ?-? 57.945 54.864 ?-? 57.944 21.992 ?-? 57.852 41.739 ?-? 57.833 67.142 ?-? 57.831 61.037 ?-? 57.797 25.111 ?-? 57.774 63.227 ?-? 57.731 62.012 ?-? 57.676 57.674 ?-? 57.628 52.988 ?-? 57.637 40.943 ?-? 57.653 31.128 ?-? 57.626 28.511 ?-? 57.596 34.026 ?-? 57.582 32.554 ?-? 57.543 54.526 ?-? 57.55 53.488 ?-? 57.524 57.534 ?-? 57.467 61.55 ?-? 57.471 41.38 ?-? 57.456 40.247 ?-? 57.434 54.038 ?-? 57.389 57.388 ?-? 57.401 54.139 ?-? 57.388 31.939 ?-? 57.361 29.221 ?-? 57.324 55.692 ?-? 57.287 59.785 ?-? 57.293 35.863 ?-? 57.314 30.628 ?-? 57.316 29.168 ?-? 57.173 65.083 ?-? 57.177 40.87 ?-? 57.119 57.109 ?-? 57.059 38.232 ?-? 57.091 18.46 ?-? 57.052 57.035 ?-? 57.04 30.142 ?-? 56.991 34.834 ?-? 56.983 27.088 ?-? 56.942 53.934 ?-? 56.967 45.497 ?-? 56.966 34.948 ?-? 56.887 53.435 ?-? 56.869 54.473 ?-? 56.865 38.134 ?-? 56.835 55.125 ?-? 56.802 33.62 ?-? 56.826 27.233 ?-? 56.784 39.997 ?-? 56.691 40.463 ?-? 56.688 38.378 ?-? 56.667 34.527 ?-? 56.629 34.091 ?-? 56.636 26.2 ?-? 56.602 35.307 ?-? 56.625 33.012 ?-? 56.621 32.258 ?-? 56.616 31.539 ?-? 56.516 41.079 ?-? 56.501 29.594 ?-? 56.494 65.804 ?-? 56.456 27.274 ?-? 56.387 33.409 ?-? 56.393 27.034 ?-? 56.327 41.301 ?-? 56.3 31.865 ?-? 56.264 65.427 ?-? 56.253 58.252 ?-? 56.215 58.032 ?-? 56.223 30.387 ?-? 56.116 56.12 ?-? 55.881 53.226 ?-? 55.854 43.218 ?-? 55.876 34.696 ?-? 55.806 55.795 ?-? 55.81 41.288 ?-? 55.824 41.219 ?-? 55.838 29.589 ?-? 55.75 32.223 ?-? 55.7 58.37 ?-? 55.69 42.256 ?-? 55.634 58.779 ?-? 55.65 32.107 ?-? 55.609 42.741 ?-? 55.603 30.462 ?-? 55.558 58.018 ?-? 55.584 31.292 ?-? 55.582 30.764 ?-? 55.531 39.916 ?-? 55.527 29.948 ?-? 55.53 25.309 ?-? 55.503 64.634 ?-? 55.481 52.981 ?-? 55.451 39.535 ?-? 55.423 36.845 ?-? 55.406 48.055 ?-? 55.319 41.677 ?-? 55.313 37.872 ?-? 55.264 48.544 ?-? 55.224 43.351 ?-? 55.169 55.175 ?-? 55.184 46.805 ?-? 55.118 50.989 ?-? 55.132 46.321 ?-? 55.126 43.807 ?-? 55.144 40.251 ?-? 55.115 29.55 ?-? 55.123 27.411 ?-? 55.112 44.407 ?-? 55.057 55.074 ?-? 55.05 41.325 ?-? 55.049 27.446 ?-? 55.064 25.729 ?-? 54.999 51.753 ?-? 55.017 40.073 ?-? 55.021 33.341 ?-? 54.976 57.565 ?-? 54.978 38.777 ?-? 54.954 25.838 ?-? 54.913 54.933 ?-? 54.878 58.929 ?-? 54.877 38.232 ?-? 54.879 31.062 ?-? 54.832 27.782 ?-? 54.788 30.075 ?-? 54.807 29.151 ?-? 54.739 39.471 ?-? 54.744 34.114 ?-? 54.753 30.748 ?-? 54.663 30.622 ?-? 54.621 46.177 ?-? 54.558 52.057 ?-? 54.558 37.733 ?-? 54.588 34.851 ?-? 54.562 32.676 ?-? 54.52 46.772 ?-? 54.52 41.51 ?-? 54.539 40.546 ?-? 54.546 35.77 ?-? 54.522 29.698 ?-? 54.494 40.08 ?-? 54.478 27.341 ?-? 54.438 54.439 ?-? 54.44 50.181 ?-? 54.446 27.99 ?-? 54.387 44.645 ?-? 54.397 33.853 ?-? 54.401 32.379 ?-? 54.424 24.013 ?-? 54.353 36.124 ?-? 54.33 51.704 ?-? 54.327 43.834 ?-? 54.266 58.013 ?-? 54.267 38.092 ?-? 54.27 25.32 ?-? 54.222 58.59 ?-? 54.234 57.484 ?-? 54.208 45.744 ?-? 54.215 27.475 ?-? 54.227 26.472 ?-? 54.177 37.267 ?-? 54.129 43.229 ?-? 54.14 25.99 ?-? 54.094 42.502 ?-? 54.1 25.556 ?-? 54.048 43.08 ?-? 54.051 32.601 ?-? 54.051 30.413 ?-? 54.07 24.295 ?-? 54.03 58.297 ?-? 54.021 42.118 ?-? 54.034 41.152 ?-? 54.02 38.257 ?-? 54.003 32.675 ?-? 53.991 25.698 ?-? 53.879 57.017 ?-? 53.843 37.381 ?-? 53.822 27.946 ?-? 53.8 40.103 ?-? 53.776 38.945 ?-? 53.682 26.883 ?-? 53.612 53.642 ?-? 53.622 50.993 ?-? 53.605 34.587 ?-? 53.634 24.09 ?-? 53.587 58.739 ?-? 53.574 26.12 ?-? 53.475 34.631 ?-? 53.465 42.463 ?-? 53.459 32.6 ?-? 53.432 26.247 ?-? 53.425 27.107 ?-? 53.381 56.746 ?-? 53.352 53.373 ?-? 53.348 36.257 ?-? 53.362 34.749 ?-? 53.37 33.33 ?-? 53.234 31.473 ?-? 53.138 55.735 ?-? 53.155 45.022 ?-? 53.115 45.163 ?-? 53.117 40.541 ?-? 53.079 37.605 ?-? 53.02 44.148 ?-? 52.979 51.076 ?-? 52.983 26.516 ?-? 52.955 44.758 ?-? 52.913 43.119 ?-? 52.93 27.363 ?-? 52.884 39.412 ?-? 52.853 43.937 ?-? 52.842 38.695 ?-? 52.71 39.886 ?-? 52.676 55.657 ?-? 52.616 41.195 ?-? 52.604 52.613 ?-? 52.492 39.155 ?-? 52.421 40.875 ?-? 52.345 52.356 ?-? 52.246 55.064 ?-? 52.243 52.245 ?-? 52.217 54.074 ?-? 52.211 38.447 ?-? 52.094 52.107 ?-? 52.026 33.573 ?-? 52.033 28.455 ?-? 51.993 52 ?-? 51.927 54.719 ?-? 51.87 19.057 ?-? 51.829 53.752 ?-? 51.742 53.61 ?-? 51.345 52.974 ?-? 51.326 27.35 ?-? 51.131 54.539 ?-? 51.082 42.498 ?-? 51.04 23.45 ?-? 51.013 20.624 ?-? 50.975 54.358 ?-? 50.987 19.308 ?-? 50.955 50.968 ?-? 50.91 52.533 ?-? 50.921 32.388 ?-? 50.925 21.371 ?-? 50.865 55.419 ?-? 50.803 31.441 ?-? 50.815 28.288 ?-? 50.774 65.342 ?-? 50.784 63.357 ?-? 50.794 31.649 ?-? 50.7 32.651 ?-? 50.585 42.007 ?-? 50.528 32.084 ?-? 50.327 50.321 ?-? 50.262 50.233 ?-? 50.205 28.262 ?-? 50.18 50.171 ?-? 50 50.045 ?-? 49.889 23.965 ?-? 49.399 48.376 ?-? 49.365 50.987 ?-? 49.298 23.432 ?-? 48.597 55.246 ?-? 48.598 48.561 ?-? 48.021 47.679 ?-? 47.885 46.488 ?-? 47.685 45.485 ?-? 47.459 45.671 ?-? 47.345 45.771 ?-? 47.171 46.035 ?-? 47.121 55.132 ?-? 46.94 46.964 ?-? 46.808 54.923 ?-? 46.623 44.839 ?-? 46.561 55.197 ?-? 46.505 54.352 ?-? 46.351 44.337 ?-? 46.342 54.505 ?-? 45.925 54.29 ?-? 45.719 45.704 ?-? 45.458 42.445 ?-? 45.378 46.821 ?-? 45.289 43.153 ?-? 45.172 54.44 ?-? 45.07 42.106 ?-? 45.03 45.007 ?-? 44.986 42.75 ?-? 44.884 53.218 ?-? 44.891 26.45 ?-? 44.765 54.21 ?-? 44.686 46.436 ?-? 44.689 27.325 ?-? 44.593 44.597 ?-? 44.492 44.493 ?-? 44.409 55.109 ?-? 44.156 26.584 ?-? 44.128 52.962 ?-? 44.02 28.188 ?-? 43.98 41.329 ?-? 43.98 41.007 ?-? 43.896 28.331 ?-? 43.714 45.275 ?-? 43.688 28.991 ?-? 43.661 41.801 ?-? 43.574 55.257 ?-? 43.563 26.196 ?-? 43.534 58.783 ?-? 43.542 40.143 ?-? 43.509 25.699 ?-? 43.438 53.001 ?-? 43.431 52.53 ?-? 43.373 54.151 ?-? 43.388 41.054 ?-? 43.377 40.643 ?-? 43.41 29.233 ?-? 43.409 27.198 ?-? 43.359 15.771 ?-? 43.313 43.307 ?-? 43.203 24.381 ?-? 43.168 56.706 ?-? 43.153 41.703 ?-? 43.039 55.284 ?-? 43.029 26.089 ?-? 42.981 40.287 ?-? 42.97 27.963 ?-? 42.938 40.245 ?-? 42.887 42.904 ?-? 42.701 53.995 ?-? 42.69 45.248 ?-? 42.665 55.684 ?-? 42.657 54.852 ?-? 42.641 54.127 ?-? 42.456 38.71 ?-? 42.419 53.701 ?-? 42.372 22.399 ?-? 42.328 26.235 ?-? 42.286 55.95 ?-? 42.254 28.189 ?-? 42.288 26.109 ?-? 42.25 25.116 ?-? 42.212 42.217 ?-? 42.218 38.365 ?-? 42.233 26.985 ?-? 42.181 31.079 ?-? 42.184 29.704 ?-? 42.163 25.96 ?-? 42.175 24.491 ?-? 42.14 37.869 ?-? 42.081 39.008 ?-? 42.033 39.331 ?-? 41.947 58.783 ?-? 41.96 28.763 ?-? 41.973 18.927 ?-? 41.908 55.577 ?-? 41.916 26.587 ?-? 41.822 24.277 ?-? 41.792 31.397 ?-? 41.776 23.414 ?-? 41.746 57.609 ?-? 41.757 53.347 ?-? 41.688 38.264 ?-? 41.685 55.061 ?-? 41.683 31.248 ?-? 41.686 26.768 ?-? 41.612 55.944 ?-? 41.615 27.643 ?-? 41.556 54.384 ?-? 41.528 51.171 ?-? 41.503 39.171 ?-? 41.466 55.187 ?-? 41.466 41.47 ?-? 41.409 28.938 ?-? 41.415 25.953 ?-? 41.378 56.569 ?-? 41.291 57.395 ?-? 41.17 43.884 ?-? 41.163 43.209 ?-? 41.127 27.962 ?-? 41.109 52.276 ?-? 41.106 25.596 ?-? 41.06 52.672 ?-? 41.038 39.554 ?-? 40.996 58.347 ?-? 40.988 56.263 ?-? 40.989 17.947 ?-? 40.929 56.001 ?-? 40.743 56.468 ?-? 40.703 38.57 ?-? 40.689 56.525 ?-? 40.682 43.763 ?-? 40.687 43.254 ?-? 40.647 57.574 ?-? 40.373 54.873 ?-? 40.355 40.373 ?-? 40.388 38.825 ?-? 40.31 42.071 ?-? 40.204 55.002 ?-? 40.141 56.752 ?-? 40.083 55.071 ?-? 40.017 55.586 ?-? 40.018 40.034 ?-? 40.01 38.055 ?-? 39.993 43.151 ?-? 39.913 56.936 ?-? 39.879 53.953 ?-? 39.869 41.389 ?-? 39.762 56.773 ?-? 39.699 56.732 ?-? 39.494 42.445 ?-? 39.446 52.95 ?-? 39.383 55.559 ?-? 39.312 39.319 ?-? 39.246 41.302 ?-? 39.178 52.605 ?-? 39.118 42.162 ?-? 38.955 52.22 ?-? 38.927 41.846 ?-? 38.943 40.661 ?-? 38.938 38.966 ?-? 38.87 38.903 ?-? 38.799 54.341 ?-? 38.735 54.373 ?-? 38.587 55.106 ?-? 38.464 54.533 ?-? 38.42 34.482 ?-? 38.329 54.204 ?-? 38.217 56.796 ?-? 38.216 18.403 ?-? 38.114 38.145 ?-? 38.077 41.288 ?-? 38.07 26.993 ?-? 38.044 38.066 ?-? 37.973 53.945 ?-? 38.004 17.124 ?-? 37.926 37.936 ?-? 37.871 63.104 ?-? 37.802 62.241 ?-? 37.744 62.282 ?-? 37.748 29.435 ?-? 37.701 37.695 ?-? 37.629 34.725 ?-? 37.635 29.287 ?-? 37.669 18.317 ?-? 37.67 17.198 ?-? 37.556 53.328 ?-? 37.291 38.798 ?-? 37.314 35.314 ?-? 37.274 30.452 ?-? 37.178 54.016 ?-? 37.186 30.478 ?-? 37.162 25.264 ?-? 37.091 55.188 ?-? 37.009 30.648 ?-? 36.938 54.965 ?-? 36.911 55.45 ?-? 36.834 35.001 ?-? 36.67 33.918 ?-? 36.621 59.04 ?-? 36.537 36.507 ?-? 36.517 22.437 ?-? 36.396 38.077 ?-? 36.418 36.389 ?-? 36.386 33.762 ?-? 36.369 55.46 ?-? 36.334 25.253 ?-? 36.306 34.548 ?-? 36.283 53.325 ?-? 36.203 30.661 ?-? 36.18 30.154 ?-? 36.093 54.371 ?-? 36.101 33.014 ?-? 36.089 31.399 ?-? 35.95 31.922 ?-? 35.929 30.877 ?-? 35.873 35.874 ?-? 35.889 25.267 ?-? 35.823 32.41 ?-? 35.822 30.492 ?-? 35.81 60.061 ?-? 35.809 20.563 ?-? 35.729 53.95 ?-? 35.704 58.724 ?-? 35.69 32.74 ?-? 35.693 31.599 ?-? 35.726 31.13 ?-? 35.665 53.418 ?-? 35.672 21.365 ?-? 35.624 32.807 ?-? 35.627 30.353 ?-? 35.567 54.828 ?-? 35.558 32.138 ?-? 35.549 53.512 ?-? 35.524 33.844 ?-? 35.553 24.513 ?-? 35.347 33.678 ?-? 35.33 18.234 ?-? 35.175 59.342 ?-? 35.135 54.98 ?-? 35.071 31.674 ?-? 35.056 23.205 ?-? 35.015 31.221 ?-? 34.96 34.966 ?-? 34.919 20.207 ?-? 34.87 56.813 ?-? 34.878 32.252 ?-? 34.874 30.086 ?-? 34.844 23.378 ?-? 34.789 22.782 ?-? 34.739 30.044 ?-? 34.777 23.422 ?-? 34.739 21.435 ?-? 34.682 60.62 ?-? 34.68 53.479 ?-? 34.65 34.674 ?-? 34.647 30.898 ?-? 34.634 26.608 ?-? 34.571 34.571 ?-? 34.574 23.819 ?-? 34.516 23.255 ?-? 34.446 31.885 ?-? 34.387 53.923 ?-? 34.223 56.709 ?-? 34.23 54.782 ?-? 34.253 34.251 ?-? 34.227 32.449 ?-? 34.248 31.269 ?-? 34.197 55.977 ?-? 34.186 19.838 ?-? 34.139 54.71 ?-? 34.136 34.16 ?-? 34.142 25.732 ?-? 34.093 57.444 ?-? 34.117 38.196 ?-? 34.122 20.821 ?-? 34.068 42.195 ?-? 34.044 31.144 ?-? 34.008 60.732 ?-? 33.999 31.607 ?-? 33.977 20.712 ?-? 33.838 54.388 ?-? 33.867 36.301 ?-? 33.87 20.572 ?-? 33.789 33.787 ?-? 33.786 30.075 ?-? 33.81 20.04 ?-? 33.752 21.661 ?-? 33.725 31.362 ?-? 33.704 20.13 ?-? 33.662 61.855 ?-? 33.663 60.641 ?-? 33.681 52.174 ?-? 33.686 25.572 ?-? 33.603 28.431 ?-? 33.602 24.913 ?-? 33.607 22.618 ?-? 33.522 51.936 ?-? 33.472 60.792 ?-? 33.451 27.671 ?-? 33.427 55.06 ?-? 33.415 33.437 ?-? 33.438 30.421 ?-? 33.379 56.185 ?-? 33.314 62.428 ?-? 33.316 29.268 ?-? 33.326 27.026 ?-? 33.304 34.94 ?-? 33.293 33.308 ?-? 33.148 53.442 ?-? 33.176 33.18 ?-? 33.102 36.424 ?-? 33.074 61.581 ?-? 33.068 61.09 ?-? 33.077 24.889 ?-? 33.059 23.198 ?-? 33.054 22.701 ?-? 33.043 27.345 ?-? 32.967 20.906 ?-? 32.943 29.86 ?-? 32.856 53.809 ?-? 32.859 30.292 ?-? 32.847 24.313 ?-? 32.751 57.887 ?-? 32.779 56.732 ?-? 32.754 30.259 ?-? 32.745 55.13 ?-? 32.718 23.834 ?-? 32.694 34.399 ?-? 32.62 35.311 ?-? 32.552 29.539 ?-? 32.522 62.955 ?-? 32.509 54.267 ?-? 32.527 50.972 ?-? 32.455 59.301 ?-? 32.458 35.476 ?-? 32.483 25.998 ?-? 32.419 66.026 ?-? 32.419 53.316 ?-? 32.409 30.494 ?-? 32.439 28.543 ?-? 32.408 24.052 ?-? 32.366 32.369 ?-? 32.377 29.893 ?-? 32.341 57.552 ?-? 32.335 56.034 ?-? 32.349 35.692 ?-? 32.347 27.333 ?-? 32.296 64.336 ?-? 32.236 56.735 ?-? 32.242 54.481 ?-? 32.227 34.25 ?-? 32.179 23.048 ?-? 32.11 35.08 ?-? 32.13 23.781 ?-? 32.067 56.403 ?-? 32.071 50.466 ?-? 32.1 17.619 ?-? 32.026 63.501 ?-? 31.971 57.208 ?-? 31.941 23.584 ?-? 31.861 28.547 ?-? 31.83 26.032 ?-? 31.691 16.974 ?-? 31.62 63.265 ?-? 31.608 55.625 ?-? 31.586 31.574 ?-? 31.557 65.437 ?-? 31.577 35.712 ?-? 31.554 35.121 ?-? 31.557 34.374 ?-? 31.453 56.66 ?-? 31.484 50.888 ?-? 31.487 31.466 ?-? 31.47 28.186 ?-? 31.47 21.969 ?-? 31.351 34.009 ?-? 31.311 55.031 ?-? 31.271 53.967 ?-? 31.268 41.692 ?-? 31.274 27.527 ?-? 31.252 23.446 ?-? 31.232 31.193 ?-? 31.192 57.68 ?-? 31.171 34.129 ?-? 31.159 24.968 ?-? 31.13 55.759 ?-? 31.091 54.869 ?-? 31.039 22.851 ?-? 30.961 34.965 ?-? 30.933 63.894 ?-? 30.931 63.011 ?-? 30.849 34.861 ?-? 30.855 28.183 ?-? 30.816 55.997 ?-? 30.807 22.002 ?-? 30.794 36.66 ?-? 30.801 35.992 ?-? 30.661 36.804 ?-? 30.61 57.271 ?-? 30.578 33.633 ?-? 30.516 63.634 ?-? 30.525 29.038 ?-? 30.493 27.801 ?-? 30.401 54.728 ?-? 30.342 37.169 ?-? 30.357 35.884 ?-? 30.296 32.834 ?-? 30.312 30.32 ?-? 30.282 35.293 ?-? 30.231 55.647 ?-? 30.241 27.281 ?-? 30.241 21.692 ?-? 30.16 55.933 ?-? 30.177 33.403 ?-? 30.155 21.615 ?-? 30.071 32.521 ?-? 29.985 55.239 ?-? 30.009 35.515 ?-? 29.924 33.164 ?-? 29.737 54.918 ?-? 29.703 56.298 ?-? 29.684 55.694 ?-? 29.7 42.168 ?-? 29.682 20.963 ?-? 29.662 54.999 ?-? 29.649 25.944 ?-? 29.665 23.88 ?-? 29.604 33.636 ?-? 29.529 37.883 ?-? 29.54 32.413 ?-? 29.48 57.259 ?-? 29.49 33.28 ?-? 29.496 26.718 ?-? 29.436 25.059 ?-? 29.432 21.396 ?-? 29.462 20.608 ?-? 29.401 55.173 ?-? 29.386 29.383 ?-? 29.422 26.925 ?-? 29.342 23.434 ?-? 29.327 54.527 ?-? 29.333 14.125 ?-? 29.268 37.752 ?-? 29.258 31.132 ?-? 29.225 23.588 ?-? 29.199 56.132 ?-? 29.129 43.088 ?-? 29.154 15.72 ?-? 29.098 56.751 ?-? 29.045 43.52 ?-? 29.072 27.317 ?-? 28.998 23.863 ?-? 29.022 20.857 ?-? 28.957 62.989 ?-? 28.929 41.479 ?-? 28.846 30.777 ?-? 28.732 58.652 ?-? 28.679 45.3 ?-? 28.675 41.969 ?-? 28.498 62.948 ?-? 28.477 32.484 ?-? 28.445 62.787 ?-? 28.443 58.886 ?-? 28.396 62.654 ?-? 28.396 62.33 ?-? 28.407 51.96 ?-? 28.388 50.838 ?-? 28.427 33.512 ?-? 28.418 26.761 ?-? 28.35 43.887 ?-? 28.305 63.352 ?-? 28.274 31.542 ?-? 28.207 24.949 ?-? 28.145 54.761 ?-? 28.068 54.702 ?-? 28.01 43.976 ?-? 27.979 41.396 ?-? 27.485 54.421 ?-? 27.507 41.47 ?-? 27.521 31.251 ?-? 27.443 55.234 ?-? 27.411 54.287 ?-? 27.407 23.298 ?-? 27.325 64.395 ?-? 27.349 51.245 ?-? 27.313 44.526 ?-? 27.344 28.947 ?-? 27.275 54.823 ?-? 27.304 32.334 ?-? 27.266 27.28 ?-? 27.285 22.729 ?-? 27.29 21.605 ?-? 27.248 56.95 ?-? 27.244 33.576 ?-? 27.241 25.535 ?-? 27.218 53.164 ?-? 27.214 29.53 ?-? 27.097 56.593 ?-? 27.125 43.394 ?-? 27.124 12.785 ?-? 27.048 24.252 ?-? 27.032 42.454 ?-? 27.03 18.464 ?-? 26.999 53.362 ?-? 26.999 42.224 ?-? 26.97 42.127 ?-? 26.979 38.047 ?-? 26.898 29.758 ?-? 26.904 23.982 ?-? 26.813 12.437 ?-? 26.672 54.195 ?-? 26.634 32.288 ?-? 26.593 53.081 ?-? 26.603 28.537 ?-? 26.558 44.913 ?-? 26.539 29.551 ?-? 26.534 23.348 ?-? 26.535 21.521 ?-? 26.437 26.441 ?-? 26.303 26.304 ?-? 26.237 44.129 ?-? 26.186 43.184 ?-? 26.221 26.2 ?-? 26.142 53.951 ?-? 26.022 59.318 ?-? 26.019 32.425 ?-? 25.997 41.563 ?-? 25.936 42.136 ?-? 25.927 29.657 ?-? 25.956 24.443 ?-? 25.767 58.625 ?-? 25.723 55.04 ?-? 25.746 34.106 ?-? 25.697 53.822 ?-? 25.683 22.628 ?-? 25.626 54.539 ?-? 25.594 34.519 ?-? 25.562 41.104 ?-? 25.565 27.287 ?-? 25.564 25.551 ?-? 25.536 36.451 ?-? 25.535 33.349 ?-? 25.524 12.319 ?-? 25.479 54.169 ?-? 25.462 43.432 ?-? 25.462 25.478 ?-? 25.4 25.396 ?-? 25.31 42.474 ?-? 25.298 36.108 ?-? 25.269 37.07 ?-? 25.269 27.096 ?-? 25.267 25.261 ?-? 25.176 22.162 ?-? 25.063 42.077 ?-? 25.084 29.424 ?-? 25.037 57.895 ?-? 24.979 31.748 ?-? 24.96 31.074 ?-? 24.89 31.606 ?-? 24.901 28.495 ?-? 24.88 33.175 ?-? 24.753 24.756 ?-? 24.603 28.422 ?-? 24.605 24.617 ?-? 24.528 24.516 ?-? 24.474 27.774 ?-? 24.407 43.3 ?-? 24.393 42.171 ?-? 24.404 24.393 ?-? 24.343 26.129 ?-? 24.297 53.954 ?-? 24.285 24.316 ?-? 24.256 53.783 ?-? 24.267 27.601 ?-? 24.066 29.087 ?-? 24.006 26.782 ?-? 24.001 25.435 ?-? 23.965 49.905 ?-? 23.977 27.262 ?-? 23.955 23.956 ?-? 23.896 32.372 ?-? 23.846 34.517 ?-? 23.853 20.72 ?-? 23.72 23.723 ?-? 23.633 41.698 ?-? 23.45 51.059 ?-? 23.459 31.233 ?-? 23.367 49.395 ?-? 23.312 73.305 ?-? 23.269 27.344 ?-? 23.225 62.539 ?-? 23.245 60.664 ?-? 23.244 34.857 ?-? 23.219 26.617 ?-? 23.169 23.178 ?-? 23.175 20.186 ?-? 23.155 26.121 ?-? 23.073 23.076 ?-? 23.036 21.225 ?-? 23.013 66 ?-? 23.012 32.286 ?-? 22.957 63.489 ?-? 22.903 22.921 ?-? 22.914 21.129 ?-? 22.918 19.769 ?-? 22.889 66.263 ?-? 22.88 17.652 ?-? 22.841 32.835 ?-? 22.787 73.273 ?-? 22.772 33.009 ?-? 22.758 27.309 ?-? 22.688 25.664 ?-? 22.657 33.74 ?-? 22.681 19.442 ?-? 22.61 61.764 ?-? 22.638 21.109 ?-? 22.625 19.947 ?-? 22.57 70.205 ?-? 22.582 22.569 ?-? 22.535 42.423 ?-? 22.5 58.798 ?-? 22.484 22.498 ?-? 22.453 25.224 ?-? 22.445 20.926 ?-? 22.413 69.506 ?-? 22.418 36.585 ?-? 22.351 20.281 ?-? 22.294 19.306 ?-? 22.237 60.457 ?-? 22.195 72.41 ?-? 22.19 22.965 ?-? 22.211 19.403 ?-? 22.202 17.92 ?-? 22.161 22.152 ?-? 22.086 36 ?-? 22.057 63.733 ?-? 22.011 30.798 ?-? 21.989 58.14 ?-? 21.934 65.848 ?-? 21.881 31.65 ?-? 21.827 72.21 ?-? 21.836 68.002 ?-? 21.834 17.035 ?-? 21.742 21.751 ?-? 21.76 17.154 ?-? 21.708 61.787 ?-? 21.711 18.584 ?-? 21.666 61.07 ?-? 21.678 21.664 ?-? 21.628 19.048 ?-? 21.605 68.737 ?-? 21.573 60.346 ?-? 21.54 70.681 ?-? 21.55 59.904 ?-? 21.549 27.23 ?-? 21.526 26.432 ?-? 21.555 21.541 ?-? 21.5 34.538 ?-? 21.409 35.547 ?-? 21.403 18.33 ?-? 21.363 34.841 ?-? 21.348 23.095 ?-? 21.364 17.871 ?-? 21.346 50.941 ?-? 21.282 23.027 ?-? 21.207 66.093 ?-? 21.164 18.568 ?-? 21.1 60.45 ?-? 21.095 21.107 ?-? 21.055 32.577 ?-? 21.073 18.01 ?-? 21.011 72.796 ?-? 21.016 60.537 ?-? 21.021 18.1 ?-? 21.032 17.291 ?-? 20.988 71.466 ?-? 20.966 20.974 ?-? 20.924 61.78 ?-? 20.9 33.065 ?-? 20.914 20.901 ?-? 20.873 18.293 ?-? 20.807 68.95 ?-? 20.795 58.552 ?-? 20.719 33.764 ?-? 20.743 20.74 ?-? 20.615 51.006 ?-? 20.588 18.615 ?-? 20.512 60.269 ?-? 20.494 35.742 ?-? 20.344 17.135 ?-? 20.268 21.75 ?-? 20.143 33.656 ?-? 20.099 18.773 ?-? 20.084 20.085 ?-? 20.025 16.577 ?-? 19.961 19.963 ?-? 19.895 23.068 ?-? 19.833 61.592 ?-? 19.786 22.685 ?-? 19.653 21.102 ?-? 19.602 19.59 ?-? 19.373 59.166 ?-? 19.346 70.902 ?-? 19.347 19.348 ?-? 19.288 22.39 ?-? 19.212 20.712 ?-? 19.23 19.223 ?-? 19.088 51.826 ?-? 19.023 19.022 ?-? 18.947 41.935 ?-? 18.844 27.394 ?-? 18.741 59.543 ?-? 18.689 21.737 ?-? 18.642 71.317 ?-? 18.504 27.059 ?-? 18.499 18.5 ?-? 18.442 38.249 ?-? 18.406 37.877 ?-? 18.374 18.376 ?-? 18.149 21.303 ?-? 18.038 68.775 ?-? 17.984 64.557 ?-? 17.997 18.003 ?-? 17.939 41.002 ?-? 17.975 35.188 ?-? 17.898 16.624 ?-? 17.856 25.563 ?-? 17.802 58.899 ?-? 17.604 32.057 ?-? 17.565 63.482 ?-? 17.52 23.031 ?-? 17.523 20.753 ?-? 17.504 17.514 ?-? 17.337 17.356 ?-? 17.22 37.825 ?-? 17.209 29.33 ?-? 17.145 17.138 ?-? 17.086 63.196 ?-? 17.025 31.682 ?-? 16.971 16.974 ?-? 16.847 16.85 ?-? 16.231 16.231 ?-? 15.804 58.339 ?-? 15.791 43.398 ?-? 15.755 29.156 ?-? 15.732 15.727 ?-? 14.311 38.048 ?-? 14.203 22.733 ?-? 14.182 14.173 ?-? 14.098 29.334 ?-? 14.078 17.062 ?-? 13.839 13.851 ?-? 13.824 22.408 ?-? 13.765 21.732 ?-? 13.47 13.472 ?-? 13.425 22.034 ?-? 13.248 21.465 ?-? 13.115 21.575 ?-? 12.732 21.307 ?-? 12.641 27.12 ?-? 12.551 20.67 ?-? 12.488 26.972 ?-? 12.327 25.549 ?-? 12.315 12.309 ?-? 184.034 37.517 ?-? 183.955 36.964 ?-? 183.802 37.844 ?-? 183.689 34.082 ?-? 183.681 33.689 ?-? 182.828 34.767 ?-? 180.529 40.422 ?-? 180.35 42.178 ?-? 180.129 41.617 ?-? 180.085 34.655 ?-? 180.016 40.01 ?-? 179.796 55.66 ?-? 179.742 33.086 ?-? 179.686 34.105 ?-? 179.562 32.564 ?-? 179.518 43.656 ?-? 179.547 41.4 ?-? 179.482 31.189 ?-? 179.232 40.163 ?-? 179.056 55.01 ?-? 179.057 40.196 ?-? 178.916 32.585 ?-? 178.788 40.843 ?-? 178.72 54.599 ?-? 178.618 41.543 ?-? 178.643 40.54 ?-? 178.592 56.655 ?-? 178.529 41.391 ?-? 178.447 37.58 ?-? 178.423 41.244 ?-? 178.356 38.122 ?-? 178.317 57.167 ?-? 178.324 32.547 ?-? 178.268 55.39 ?-? 178.286 40.901 ?-? 178.266 29.75 ?-? 178.239 27.883 ?-? 178.243 27.146 ?-? 178.238 25.971 ?-? 178.212 36.257 ?-? 178.178 27.814 ?-? 178.162 53.96 ?-? 178.145 29.833 ?-? 178.061 63.192 ?-? 178.058 42.577 ?-? 178.079 36.141 ?-? 178.054 29.918 ?-? 178.046 35.345 ?-? 178.009 33.683 ?-? 178.039 31.687 ?-? 177.989 57.557 ?-? 177.979 29.981 ?-? 177.942 28.223 ?-? 177.814 38.342 ?-? 177.789 37.417 ?-? 177.825 34.226 ?-? 177.757 59.313 ?-? 177.781 37.951 ?-? 177.708 25.196 ?-? 177.662 55.176 ?-? 177.621 53.773 ?-? 177.612 63.404 ?-? 177.589 60.189 ?-? 177.609 59.52 ?-? 177.613 36.898 ?-? 177.579 33.036 ?-? 177.551 53.634 ?-? 177.531 37.367 ?-? 177.481 50.85 ?-? 177.444 41.801 ?-? 177.45 37.421 ?-? 177.457 32.412 ?-? 177.421 59.072 ?-? 177.425 35.972 ?-? 177.405 23.125 ?-? 177.38 52.448 ?-? 177.395 41.835 ?-? 177.388 37.468 ?-? 177.305 28.601 ?-? 177.199 26.903 ?-? 177.178 63.983 ?-? 177.144 57.733 ?-? 177.148 40.01 ?-? 177.163 31.26 ?-? 177.146 27.375 ?-? 177.175 25.071 ?-? 177.161 22.644 ?-? 177.135 62.494 ?-? 177.103 56.924 ?-? 177.106 40.871 ?-? 177.124 32.951 ?-? 177.096 57.667 ?-? 177.028 41.318 ?-? 177.041 37.925 ?-? 176.984 63.186 ?-? 176.984 36.327 ?-? 176.934 58.614 ?-? 176.952 52.563 ?-? 176.935 38.497 ?-? 176.886 23.689 ?-? 176.875 39.653 ?-? 176.853 38.812 ?-? 176.817 23.132 ?-? 176.789 54.518 ?-? 176.763 32.146 ?-? 176.742 37.33 ?-? 176.7 51.31 ?-? 176.689 39.951 ?-? 176.588 37.054 ?-? 176.547 61.596 ?-? 176.538 59.242 ?-? 176.577 54.083 ?-? 176.554 42.821 ?-? 176.577 28.658 ?-? 176.506 57.247 ?-? 176.528 34.915 ?-? 176.521 33.013 ?-? 176.526 27.142 ?-? 176.517 25.448 ?-? 176.48 41.592 ?-? 176.41 35.23 ?-? 176.425 30.711 ?-? 176.414 25.784 ?-? 176.422 20.605 ?-? 176.368 60.804 ?-? 176.364 56.459 ?-? 176.388 34.151 ?-? 176.322 59.055 ?-? 176.329 20.829 ?-? 176.306 63.081 ?-? 176.281 38.798 ?-? 176.281 31.615 ?-? 176.252 40.601 ?-? 176.192 54.268 ?-? 176.227 43.21 ?-? 176.206 35.954 ?-? 176.183 58.818 ?-? 176.164 43.45 ?-? 176.153 39.858 ?-? 176.178 33.762 ?-? 176.152 29.866 ?-? 176.137 27.486 ?-? 176.097 55.181 ?-? 176.07 40.077 ?-? 176.074 37.527 ?-? 176.076 26.991 ?-? 176.038 51.822 ?-? 176.035 23.963 ?-? 175.955 39.317 ?-? 175.934 23.903 ?-? 175.891 29.259 ?-? 175.845 42.725 ?-? 175.835 37.107 ?-? 175.819 21.361 ?-? 175.769 42.087 ?-? 175.796 20.589 ?-? 175.747 23.812 ?-? 175.715 44.178 ?-? 175.678 20.011 ?-? 175.67 42.417 ?-? 175.646 39.094 ?-? 175.613 57.599 ?-? 175.596 31.372 ?-? 175.621 29.673 ?-? 175.565 33.567 ?-? 175.522 61.817 ?-? 175.523 52.466 ?-? 175.509 40.96 ?-? 175.468 63.645 ?-? 175.486 55.897 ?-? 175.474 43.191 ?-? 175.472 36.238 ?-? 175.486 33.651 ?-? 175.493 30.613 ?-? 175.442 53.503 ?-? 175.415 39.698 ?-? 175.425 33.235 ?-? 175.441 32.711 ?-? 175.422 32.207 ?-? 175.375 51.05 ?-? 175.403 41.556 ?-? 175.337 40.346 ?-? 175.322 38.008 ?-? 175.305 36.598 ?-? 175.29 35.801 ?-? 175.277 60.538 ?-? 175.244 29.311 ?-? 175.27 20.696 ?-? 175.257 18.297 ?-? 175.262 17.588 ?-? 175.225 24.188 ?-? 175.191 25.67 ?-? 175.146 35.662 ?-? 175.027 38.641 ?-? 175.033 33.938 ?-? 175.059 27.286 ?-? 175.051 19.934 ?-? 174.951 57.763 ?-? 174.954 53.033 ?-? 174.941 39.296 ?-? 174.98 37.849 ?-? 174.944 33.834 ?-? 174.981 26.648 ?-? 174.93 41.378 ?-? 174.926 22.667 ?-? 174.86 65.049 ?-? 174.864 63.137 ?-? 174.859 61.722 ?-? 174.856 59.105 ?-? 174.862 56.992 ?-? 174.863 29.599 ?-? 174.846 27.021 ?-? 174.843 22.607 ?-? 174.793 56.405 ?-? 174.789 43.952 ?-? 174.725 44.946 ?-? 174.76 43.474 ?-? 174.718 45.835 ?-? 174.682 42.927 ?-? 174.68 37.197 ?-? 174.707 36.61 ?-? 174.707 32.439 ?-? 174.668 64.619 ?-? 174.673 44.891 ?-? 174.665 35.197 ?-? 174.642 27.591 ?-? 174.642 20.967 ?-? 174.635 38.731 ?-? 174.603 32.153 ?-? 174.587 55.336 ?-? 174.581 42.144 ?-? 174.565 40.989 ?-? 174.522 63.765 ?-? 174.507 31.056 ?-? 174.535 28.48 ?-? 174.469 49.971 ?-? 174.466 27.399 ?-? 174.444 54.464 ?-? 174.432 48.515 ?-? 174.461 45.509 ?-? 174.448 30.558 ?-? 174.438 22.326 ?-? 174.41 69.677 ?-? 174.413 42.417 ?-? 174.358 41.536 ?-? 174.352 31.538 ?-? 174.344 23.1 ?-? 174.308 58.612 ?-? 174.27 39.818 ?-? 174.278 34.27 ?-? 174.224 41.935 ?-? 174.239 33.627 ?-? 174.148 36.43 ?-? 174.112 44.002 ?-? 174.084 40.082 ?-? 174.106 35.875 ?-? 174.062 32.49 ?-? 174 34.8 ?-? 173.991 21.483 ?-? 173.976 61.735 ?-? 173.951 51.037 ?-? 173.947 44.678 ?-? 173.938 49.922 ?-? 173.893 68.952 ?-? 173.883 60.477 ?-? 173.87 57.538 ?-? 173.865 40.953 ?-? 173.888 20.989 ?-? 173.849 63.627 ?-? 173.8 45.704 ?-? 173.734 32.975 ?-? 173.698 42.331 ?-? 173.687 32.173 ?-? 173.699 22.625 ?-? 173.708 20.489 ?-? 173.675 46.22 ?-? 173.648 43.861 ?-? 173.578 45.773 ?-? 173.582 43.899 ?-? 173.537 59.487 ?-? 173.487 41.612 ?-? 173.44 44.008 ?-? 173.463 22.22 ?-? 173.402 34.031 ?-? 173.361 35.329 ?-? 173.358 32.475 ?-? 173.34 52.276 ?-? 173.257 55.996 ?-? 173.287 39.19 ?-? 173.232 35.22 ?-? 173.195 62.539 ?-? 173.18 45.517 ?-? 173.145 60.572 ?-? 173.161 35.154 ?-? 173.102 21.968 ?-? 173.07 61.355 ?-? 173.047 21.68 ?-? 173.032 59.218 ?-? 173.026 55.221 ?-? 172.983 60.875 ?-? 172.942 59.359 ?-? 172.95 55.16 ?-? 172.942 32.802 ?-? 172.923 22.073 ?-? 172.868 54.481 ?-? 172.871 32.028 ?-? 172.857 44.412 ?-? 172.865 32.732 ?-? 172.798 42.162 ?-? 172.637 62.439 ?-? 172.605 59.723 ?-? 172.596 32.307 ?-? 172.478 56.291 ?-? 172.49 53.314 ?-? 172.358 66.411 ?-? 172.349 29.437 ?-? 172.235 61.062 ?-? 172.227 58.337 ?-? 172.185 56.85 ?-? 172.214 30.053 ?-? 172.137 65.637 ?-? 172.071 70.922 ?-? 172.07 56.97 ?-? 171.981 65.921 ?-? 171.817 57.692 ?-? 171.762 65.094 ?-? 171.727 55.577 ?-? 171.061 19.425 ?-? 72.905 175.034 ?-? 72.529 173.82 ?-? 72.241 170.513 ?-? 70.977 172.458 ?-? 70.213 173.548 ?-? 69.326 174.948 ?-? 69.063 173.856 ?-? 68.006 172.879 ?-? 66.367 172.41 ?-? 65.832 172.098 ?-? 65.171 172.533 ?-? 65.083 171.697 ?-? 64.76 174.709 ?-? 64.347 177.387 ?-? 63.82 174.46 ?-? 63.655 175.495 ?-? 63.367 177.646 ?-? 63.286 177.791 ?-? 63.118 174.928 ?-? 63.069 178.294 ?-? 63.098 176.324 ?-? 62.841 176.874 ?-? 62.817 173.003 ?-? 62.48 177.127 ?-? 62.147 172.419 ?-? 61.815 175.449 ?-? 61.729 174.853 ?-? 61.762 174.024 ?-? 61.496 177.485 ?-? 61.369 173.014 ?-? 61.103 172.216 ?-? 60.752 173.048 ?-? 60.72 176.406 ?-? 60.589 175.25 ?-? 60.423 173.914 ?-? 60.298 177.531 ?-? 59.889 172.838 ?-? 59.89 172.301 ?-? 59.641 172.543 ?-? 59.362 173.279 ?-? 59.284 173.522 ?-? 59.194 174.853 ?-? 59.135 177.517 ?-? 59.07 176.324 ?-? 58.852 177.77 ?-? 58.661 174.332 ?-? 58.619 176.048 ?-? 58.63 173.116 ?-? 58.513 176.215 ?-? 58.434 178.545 ?-? 58.326 172.275 ?-? 57.919 174.127 ?-? 57.782 174.937 ?-? 57.717 177.115 ?-? 57.625 175.567 ?-? 57.648 171.815 ?-? 57.471 173.068 ?-? 57.439 173.924 ?-? 57.216 176.521 ?-? 57.178 181.215 ?-? 57.142 178.167 ?-? 56.981 174.965 ?-? 56.909 179.858 ?-? 56.928 177.052 ?-? 56.907 172.179 ?-? 56.88 177.976 ?-? 56.829 172.267 ?-? 56.614 179.593 ?-? 56.564 176.453 ?-? 56.369 172.707 ?-? 56.335 173.133 ?-? 56.004 171.871 ?-? 55.816 178.363 ?-? 55.802 179.867 ?-? 55.262 174.691 ?-? 55.224 176.047 ?-? 55.099 179.227 ?-? 55.03 179.096 ?-? 54.656 178.692 ?-? 54.537 176.797 ?-? 54.475 172.894 ?-? 54.46 174.469 ?-? 54.3 176.04 ?-? 54.281 176.137 ?-? 53.921 179.705 ?-? 53.561 175.347 ?-? 53.528 180.414 ?-? 53.542 177.394 ?-? 53.486 178.177 ?-? 53.422 175.454 ?-? 53.361 184.13 ?-? 53.269 172.467 ?-? 53.057 174.997 ?-? 52.742 179.592 ?-? 52.7 172.855 ?-? 52.502 176.834 ?-? 52.238 173.448 ?-? 51.897 174.123 ?-? 51.87 175.986 ?-? 51.115 174.06 ?-? 51.078 175.362 ?-? 51.08 174.272 ?-? 51.017 177.679 ?-? 49.948 174.037 ?-? 46.892 177.692 ?-? 46.768 174.422 ?-? 46.361 172.996 ?-? 46.282 173.052 ?-? 46.089 174.354 ?-? 45.842 173.519 ?-? 45.777 173.908 ?-? 45.51 175.425 ?-? 45.438 174.351 ?-? 45.396 175.352 ?-? 45.199 176.904 ?-? 45.111 173.235 ?-? 45.069 177.034 ?-? 44.926 177.092 ?-? 44.849 177.114 ?-? 44.868 174.318 ?-? 44.731 174.693 ?-? 44.687 175.336 ?-? 44.583 176.837 ?-? 44.619 173.781 ?-? 44.463 172.862 ?-? 44.067 175.315 ?-? 44.064 174.682 ?-? 44.026 176.001 ?-? 43.838 175.642 ?-? 43.652 174.74 ?-? 43.507 179.506 ?-? 43.488 176.149 ?-? 43.479 173.823 ?-? 43.414 176.039 ?-? 43.299 174.316 ?-? 43.265 172.832 ?-? 43.204 176.81 ?-? 43.162 176.433 ?-? 43.076 176.679 ?-? 43.107 176.487 ?-? 42.975 175.342 ?-? 42.889 175.435 ?-? 42.868 174.667 ?-? 42.737 176.166 ?-? 42.702 178.249 ?-? 42.689 177.604 ?-? 42.655 174.475 ?-? 42.482 175.833 ?-? 42.386 174.76 ?-? 42.137 180.348 ?-? 42.082 177.273 ?-? 42.024 176.208 ?-? 41.993 174.329 ?-? 41.775 177.355 ?-? 41.694 177.518 ?-? 41.643 175.362 ?-? 41.644 173.566 ?-? 41.626 177.133 ?-? 41.575 178.588 ?-? 41.561 176.845 ?-? 41.543 179.762 ?-? 41.385 179.483 ?-? 41.15 174.8 ?-? 41.158 174.516 ?-? 41.103 174.71 ?-? 40.844 175.521 ?-? 40.744 175.47 ?-? 40.593 173.836 ?-? 40.526 180.399 ?-? 40.417 177.262 ?-? 40.289 177.114 ?-? 40.287 174.483 ?-? 40.181 179.231 ?-? 40.177 177.018 ?-? 40.164 174.676 ?-? 39.987 175.97 ?-? 39.967 175.353 ?-? 39.92 176.148 ?-? 39.872 179.963 ?-? 39.708 174.359 ?-? 39.627 177.142 ?-? 39.359 173.455 ?-? 39.327 175.746 ?-? 39.146 176.239 ?-? 39.049 174.457 ?-? 38.929 174.698 ?-? 38.821 175.927 ?-? 38.676 178.729 ?-? 38.695 177.995 ?-? 38.7 175.001 ?-? 38.524 176.867 ?-? 38.236 174.699 ?-? 38.157 178.37 ?-? 38.161 177.537 ?-? 38.032 178.048 ?-? 37.975 178.482 ?-? 37.936 175.44 ?-? 37.959 175.355 ?-? 37.892 176.615 ?-? 37.927 175.027 ?-? 37.79 178.358 ?-? 37.774 176.016 ?-? 37.725 176.18 ?-? 37.563 175.455 ?-? 37.526 174.019 ?-? 37.441 174.87 ?-? 37.406 178.572 ?-? 37.355 177.51 ?-? 37.302 173.835 ?-? 37.255 184.031 ?-? 37.275 177.93 ?-? 37.07 178.191 ?-? 37.103 175.983 ?-? 37.038 176.174 ?-? 36.954 176.425 ?-? 36.7 177.163 ?-? 36.595 174.515 ?-? 36.575 177.66 ?-? 36.543 183.584 ?-? 36.532 174.813 ?-? 36.352 178.164 ?-? 36.247 175.467 ?-? 36.068 178 ?-? 36.052 177.143 ?-? 35.967 176.198 ?-? 35.929 174.108 ?-? 35.824 174.673 ?-? 35.508 176.703 ?-? 35.43 175.309 ?-? 35.268 177.663 ?-? 35.237 176.533 ?-? 35.196 182.816 ?-? 35.169 178.129 ?-? 35.009 174.688 ?-? 34.986 174.005 ?-? 34.922 176.284 ?-? 34.544 176.015 ?-? 34.49 177.032 ?-? 34.437 177.786 ?-? 34.368 181.19 ?-? 34.381 175.055 ?-? 34.327 174.162 ?-? 34.281 179.959 ?-? 34.287 177.888 ?-? 34.179 183.863 ?-? 34.098 179.641 ?-? 34.082 182.746 ?-? 34.054 178.845 ?-? 33.912 175.981 ?-? 33.863 183.628 ?-? 33.778 177.079 ?-? 33.771 174.809 ?-? 33.703 180.38 ?-? 33.72 176.357 ?-? 33.649 177.988 ?-? 33.635 174.656 ?-? 33.572 174.555 ?-? 33.47 178.089 ?-? 33.376 178.678 ?-? 33.238 172.834 ?-? 33.099 176.616 ?-? 33.009 179.674 ?-? 33.045 177.101 ?-? 32.986 177.403 ?-? 32.963 183.979 ?-? 32.89 175.404 ?-? 32.735 182.637 ?-? 32.635 173.835 ?-? 32.616 183.133 ?-? 32.451 179.517 ?-? 32.39 178.546 ?-? 32.342 177.514 ?-? 32.306 178.03 ?-? 32.282 177.082 ?-? 32.241 180.341 ?-? 32.246 175.447 ?-? 32.224 172.606 ?-? 32.108 184.074 ?-? 32.125 173.427 ?-? 32.017 176.199 ?-? 32.003 172.88 ?-? 31.88 174.499 ?-? 31.848 172.35 ?-? 31.667 180.052 ?-? 31.597 178.066 ?-? 31.295 179.662 ?-? 31.179 177.12 ?-? 31.137 175.904 ?-? 30.993 176.022 ?-? 30.831 179.484 ?-? 30.791 182.737 ?-? 30.778 176.427 ?-? 30.675 174.398 ?-? 30.593 183.103 ?-? 30.474 174.671 ?-? 30.382 180.761 ?-? 30.352 172.534 ?-? 30.305 180.599 ?-? 30.32 174.386 ?-? 30.129 175.499 ?-? 30.07 175.62 ?-? 29.929 176.017 ?-? 29.911 172.194 ?-? 29.878 178.251 ?-? 29.765 178.02 ?-? 29.689 176.461 ?-? 29.527 179.315 ?-? 29.544 175.397 ?-? 29.394 175.673 ?-? 29.404 174.993 ?-? 29.348 175.76 ?-? 29.183 172.401 ?-? 29.067 174.563 ?-? 28.991 176.662 ?-? 28.548 179.523 ?-? 28.465 174.483 ?-? 28.41 176.818 ?-? 28.144 178.115 ?-? 27.598 176.025 ?-? 27.545 178.182 ?-? 27.36 174.359 ?-? 27.317 177.242 ?-? 27.308 177.153 ?-? 27.345 175.34 ?-? 27.329 174.463 ?-? 27.279 174.665 ?-? 27.25 176.846 ?-? 27.032 179.828 ?-? 26.979 175.677 ?-? 26.536 174.799 ?-? 25.982 176.758 ?-? 25.856 174.88 ?-? 25.81 178.582 ?-? 25.735 178.626 ?-? 25.437 176.242 ?-? 25.106 177.167 ?-? 24.046 175.986 ?-? 23.31 177.047 ?-? 23.122 177.283 ?-? 23.07 177.36 ?-? 22.753 177.056 ?-? 22.654 175.006 ?-? 22.559 175.79 ?-? 22.575 173.647 ?-? 22.466 174.666 ?-? 22.272 174.275 ?-? 22.159 177.056 ?-? 22.021 173.12 ?-? 21.871 178.291 ?-? 21.795 172.707 ?-? 21.63 174.972 ?-? 21.544 174.018 ?-? 21.442 175.514 ?-? 21.337 175.793 ?-? 21.232 174.523 ?-? 21.071 176.211 ?-? 20.89 175.081 ?-? 20.849 173.814 ?-? 20.787 175.339 ?-? 20.597 176.042 ?-? 20.569 176.18 ?-? 20.03 175.646 ?-? 19.895 175.105 ?-? 19.828 175.257 ?-? 19.39 171.125 ?-? 19.123 176.157 ?-? 172.19 72.643 ?-? 72.554 172.203 ?-? 174.534 71.454 ?-? 174.39 19.067 ?-? 71.432 174.546 ?-? 174.735 69.381 ?-? 178.467 59.24 ?-? 59.232 178.432 ?-? 175.988 50.003 ?-? 49.939 176.015 ?-? 178.154 65.452 ?-? 177.196 44.55 ?-? 173.178 64.523 ?-? 173.217 68.82 ?-? 173.268 18.003 ?-? 64.538 173.177 ?-? 68.84 173.285 ?-? 17.963 173.241 ?-? 174.03 72.3 ?-? 72.228 174.143 ?-? 70.76 173.946 ?-? 179.57 58.739 ?-? 58.736 179.553 ?-? 177.49 66.05 ?-? 66.01 177.539 ?-? 175.959 47.031 ?-? 47.016 175.967 ?-? 175.278 23.448 ?-? 23.475 175.244 ?-? 171.077 59.133 ?-? 171.082 70.894 ?-? 59.055 171.061 ?-? 70.858 171.111 ?-? 177.405 64.376 ?-? 170.615 63.544 ?-? 170.596 72.292 ?-? 170.581 22.203 ?-? 63.6 170.665 ?-? 72.484 170.807 ?-? 22.216 170.653 ?-? 44.571 177.292 ; loop_ _Spectral_dim.ID _Spectral_dim.Atom_type _Spectral_dim.Atom_isotope_number _Spectral_dim.Spectral_region _Spectral_dim.Magnetization_linkage_ID _Spectral_dim.Under_sampling_type _Spectral_dim.Sweep_width _Spectral_dim.Sweep_width_units _Spectral_dim.Center_frequency_offset _Spectral_dim.Encoding_code _Spectral_dim.Encoded_reduced_dimension_ID _Spectral_dim.Entry_ID _Spectral_dim.Spectral_peak_list_ID 2 C 13 CA . . 100000 Hz . . . 26891 2 stop_ save_ save_13C-13C_2D_DARR_AMS _Spectral_peak_list.Sf_category spectral_peak_list _Spectral_peak_list.Sf_framecode 13C-13C_2D_DARR_AMS _Spectral_peak_list.Entry_ID 26891 _Spectral_peak_list.ID 3 _Spectral_peak_list.Sample_ID 3 _Spectral_peak_list.Sample_label $sample_3 _Spectral_peak_list.Sample_condition_list_ID 3 _Spectral_peak_list.Sample_condition_list_label $sample_conditions_3 _Spectral_peak_list.Experiment_ID 3 _Spectral_peak_list.Experiment_name '2D 13C-13C DARR' _Spectral_peak_list.Number_of_spectral_dimensions 2 _Spectral_peak_list.Details . _Spectral_peak_list.Text_data_format text _Spectral_peak_list.Text_data ; Assignment w1 w2 ?-? 170.215 73.926 ?-? 72.838 59.65 ?-? 72.472 60.916 ?-? 72.39 63.524 ?-? 72.343 61.329 ?-? 72.217 61.964 ?-? 72.155 63.315 ?-? 71.394 61.96 ?-? 71.227 59.269 ?-? 70.716 60.97 ?-? 70.487 61.381 ?-? 70.452 62.191 ?-? 70.231 62.004 ?-? 69.739 61.943 ?-? 69.252 65.371 ?-? 69.106 61.419 ?-? 68.979 60.101 ?-? 68.913 58.324 ?-? 68.89 58.663 ?-? 68.74 64.696 ?-? 68.653 64.369 ?-? 72.628 172.123 ?-? 72.453 173.601 ?-? 72.36 173.691 ?-? 72.215 170.742 ?-? 71.416 174.116 ?-? 71.339 174.432 ?-? 70.717 172.055 ?-? 70.524 173.706 ?-? 70.305 173.451 ?-? 69.53 174.253 ?-? 69.231 174.731 ?-? 69.006 174.867 ?-? 68.84 174.098 ?-? 68.664 174.371 ?-? 67.879 180.181 ?-? 67.098 174.786 ?-? 66.273 172.21 ?-? 65.905 178.82 ?-? 65.857 172.004 ?-? 65.071 174.834 ?-? 64.991 171.676 ?-? 64.711 174.63 ?-? 64.709 173.032 ?-? 64.523 174.437 ?-? 64.339 177.142 ?-? 64.088 175.057 ?-? 63.488 171.727 ?-? 63.444 177.705 ?-? 63.409 170.689 ?-? 63.376 176.953 ?-? 63.31 176.856 ?-? 63.315 174.583 ?-? 63.256 177.47 ?-? 63.159 175.881 ?-? 63.141 171.411 ?-? 63.119 177.321 ?-? 63.102 171.858 ?-? 63.089 171.013 ?-? 63.03 177.865 ?-? 63 170.94 ?-? 62.755 179.142 ?-? 62.186 182.978 ?-? 62.137 176.319 ?-? 62.165 174.541 ?-? 62.133 173.882 ?-? 62.05 174.469 ?-? 61.865 177.746 ?-? 61.908 175.445 ?-? 61.899 173.667 ?-? 61.841 174.144 ?-? 61.689 173.398 ?-? 61.56 174.995 ?-? 61.442 171.752 ?-? 61.08 172.12 ?-? 61.048 175.737 ?-? 60.757 176.242 ?-? 60.633 173.073 ?-? 60.498 175.289 ?-? 60.516 172.877 ?-? 60.372 173.656 ?-? 60.299 177.62 ?-? 60.256 173.355 ?-? 60.141 173.979 ?-? 60.125 172.333 ?-? 59.953 172.529 ?-? 59.547 174.77 ?-? 59.427 178.31 ?-? 59.299 178.199 ?-? 59.167 175.175 ?-? 59.189 174.818 ?-? 59.087 171.148 ?-? 59.052 174.299 ?-? 58.97 177.05 ?-? 58.935 175.342 ?-? 58.767 179.324 ?-? 58.687 174.659 ?-? 58.656 173.969 ?-? 58.322 172.355 ?-? 58.198 172.044 ?-? 57.94 174.57 ?-? 57.843 171.657 ?-? 57.79 176.918 ?-? 57.718 175.902 ?-? 57.712 171.489 ?-? 57.676 177.843 ?-? 57.658 174.837 ?-? 57.625 177.075 ?-? 57.642 175.553 ?-? 57.625 171.845 ?-? 57.434 175.088 ?-? 57.333 176.305 ?-? 57.258 179.372 ?-? 57.257 178.355 ?-? 57.232 171.693 ?-? 57.087 174.716 ?-? 57.034 172.07 ?-? 56.954 177.767 ?-? 56.938 177.045 ?-? 56.873 175.022 ?-? 56.833 178.1 ?-? 56.851 175.948 ?-? 56.81 172.171 ?-? 56.758 176.924 ?-? 56.709 176.03 ?-? 56.589 174.871 ?-? 56.334 173.525 ?-? 56.161 176.285 ?-? 55.975 174.702 ?-? 55.894 173.359 ?-? 55.791 175.615 ?-? 55.755 180.01 ?-? 55.676 175.171 ?-? 55.564 174.585 ?-? 55.514 174.103 ?-? 55.389 174.926 ?-? 55.264 177.497 ?-? 55.303 173.025 ?-? 55.086 175.879 ?-? 55.074 173.961 ?-? 55.01 179.234 ?-? 55.025 177.334 ?-? 54.915 178.832 ?-? 54.888 172.693 ?-? 54.846 177.62 ?-? 54.8 175.676 ?-? 54.745 179.932 ?-? 54.748 176.67 ?-? 54.633 178.697 ?-? 54.607 178.287 ?-? 54.572 172.46 ?-? 54.534 180.377 ?-? 54.478 174.64 ?-? 54.412 177.917 ?-? 54.369 176.184 ?-? 54.37 176.081 ?-? 54.358 175.57 ?-? 54.379 174.087 ?-? 54.372 172.779 ?-? 54.328 180.133 ?-? 54.332 173.679 ?-? 54.221 177.76 ?-? 54.274 175.296 ?-? 54.254 174.985 ?-? 54.129 176.7 ?-? 53.953 177.952 ?-? 53.645 184.635 ?-? 53.684 177.256 ?-? 53.575 176.925 ?-? 53.603 175.507 ?-? 53.514 174.352 ?-? 53.461 177.456 ?-? 53.488 175.401 ?-? 53.389 177.992 ?-? 53.393 177.028 ?-? 53.231 177.881 ?-? 53.228 177.114 ?-? 53.155 175.134 ?-? 53.074 172.442 ?-? 53.02 173.83 ?-? 52.977 175.022 ?-? 52.888 174.464 ?-? 52.739 179.654 ?-? 52.349 175.625 ?-? 51.804 174.355 ?-? 51.057 175.257 ?-? 51.001 175.463 ?-? 46.94 175.921 ?-? 45.993 173.278 ?-? 45.867 173.153 ?-? 44.909 172.538 ?-? 44.724 173.956 ?-? 44.523 172.739 ?-? 44.417 172.852 ?-? 44.349 177.299 ?-? 44.247 176.895 ?-? 43.965 172.616 ?-? 43.558 176.215 ?-? 43.271 175.852 ?-? 43.123 176.585 ?-? 43.109 176.117 ?-? 43.072 175.753 ?-? 42.904 175.567 ?-? 42.831 175.44 ?-? 42.38 175.602 ?-? 42.349 175.086 ?-? 42.199 177.742 ?-? 42.017 175.692 ?-? 41.96 174.795 ?-? 41.773 174.299 ?-? 41.684 175.272 ?-? 41.643 173.537 ?-? 41.581 179.988 ?-? 41.542 175.132 ?-? 41.427 175.587 ?-? 41.306 179.475 ?-? 41.203 174.792 ?-? 41.203 174.051 ?-? 41.074 175.995 ?-? 40.952 175.469 ?-? 40.96 174.547 ?-? 40.795 180.222 ?-? 40.807 173.523 ?-? 40.694 178.785 ?-? 40.338 179.957 ?-? 40.278 179.122 ?-? 40.254 175.784 ?-? 40.026 176.199 ?-? 40.042 175.276 ?-? 39.975 180.212 ?-? 39.989 179.729 ?-? 39.961 178.786 ?-? 39.81 180.133 ?-? 39.819 175.888 ?-? 38.859 182.265 ?-? 37.795 175.259 ?-? 36.631 174.279 ?-? 36.605 183.809 ?-? 36.492 184.582 ?-? 36.48 175.046 ?-? 36.466 174.101 ?-? 36.406 183.926 ?-? 36.434 183.384 ?-? 36.203 184.153 ?-? 36.146 182.485 ?-? 35.959 182.373 ?-? 35.837 176.294 ?-? 35.614 173.931 ?-? 35.557 184.378 ?-? 35.486 183.541 ?-? 35.187 176.683 ?-? 35.023 183.82 ?-? 34.85 175.64 ?-? 34.729 184.144 ?-? 34.597 173.88 ?-? 34.516 175.265 ?-? 34.401 175.184 ?-? 34.369 174.42 ?-? 34.344 179.974 ?-? 34.328 174.015 ?-? 34.349 173.675 ?-? 34.231 175.471 ?-? 33.999 175.771 ?-? 33.853 174.909 ?-? 33.808 183.52 ?-? 33.67 179.557 ?-? 33.586 179.482 ?-? 33.471 180.782 ?-? 33.388 174.345 ?-? 33.31 184.236 ?-? 33.288 176.039 ?-? 33.247 180.462 ?-? 33.246 175.313 ?-? 33.136 175.38 ?-? 33.137 174.116 ?-? 32.919 176.785 ?-? 32.872 179.922 ?-? 32.84 175.577 ?-? 32.709 176.353 ?-? 32.729 175.542 ?-? 32.669 178.956 ?-? 32.496 179.24 ?-? 32.458 177.162 ?-? 32.235 177.529 ?-? 32.299 175.264 ?-? 32.156 175.581 ?-? 31.88 183.469 ?-? 31.899 175.339 ?-? 31.604 177.851 ?-? 31.556 179.127 ?-? 31.342 175.538 ?-? 31.227 177.064 ?-? 31.141 175.007 ?-? 31.067 174.956 ?-? 30.931 177.139 ?-? 30.521 182.695 ?-? 30.528 176.563 ?-? 30.34 180.47 ?-? 28.242 174.439 ?-? 27.951 176.693 ?-? 27.527 176.922 ?-? 27.396 177.013 ?-? 27.332 176.709 ?-? 27.152 177.138 ?-? 27.136 175.037 ?-? 26.567 174.358 ?-? 26.447 174.671 ?-? 26 176.645 ?-? 25.844 177.937 ?-? 25.076 176.952 ?-? 24.082 175.777 ?-? 23.839 175.436 ?-? 23.424 177.126 ?-? 23.357 175.226 ?-? 23.194 177.31 ?-? 23.247 173.908 ?-? 22.988 177.484 ?-? 22.879 173.548 ?-? 22.855 175.82 ?-? 22.766 173.501 ?-? 22.628 174.784 ?-? 22.482 176.688 ?-? 22.491 175.089 ?-? 22.403 175.201 ?-? 22.265 176.799 ?-? 22.245 174.116 ?-? 22.224 170.691 ?-? 22.065 172.975 ?-? 21.993 174.373 ?-? 21.896 172.154 ?-? 21.863 173.903 ?-? 21.818 178.105 ?-? 21.811 177.769 ?-? 21.715 178.023 ?-? 21.738 172.763 ?-? 21.677 174.703 ?-? 21.528 173.711 ?-? 21.341 175.412 ?-? 21.266 173.977 ?-? 21.2 175.573 ?-? 21.211 174.356 ?-? 20.975 177.056 ?-? 20.896 176.054 ?-? 20.904 174.673 ?-? 20.831 175.094 ?-? 20.675 175.451 ?-? 20.719 172.119 ?-? 20.426 176.414 ?-? 20.346 173.883 ?-? 20.269 176.2 ?-? 19.822 174.915 ?-? 19.794 175.15 ?-? 19.351 173.907 ?-? 19.231 171.041 ?-? 18.926 170.713 ?-? 18.857 171.392 ?-? 18.707 174.426 ?-? 18.609 174.138 ?-? 18.375 175.124 ?-? 18.07 175.733 ?-? 17.978 174.471 ?-? 16.511 177.85 ?-? 15.844 172.045 ?-? 73.211 22.116 ?-? 73.002 73.043 ?-? 72.994 22.463 ?-? 72.427 20.588 ?-? 72.332 72.358 ?-? 72.169 21.955 ?-? 71.448 21.066 ?-? 71.381 71.364 ?-? 71.313 18.609 ?-? 70.901 19.164 ?-? 70.748 19.243 ?-? 70.689 70.673 ?-? 70.63 21.787 ?-? 70.325 70.303 ?-? 70.256 23.02 ?-? 70.306 16.001 ?-? 70.047 70.058 ?-? 69.881 19.786 ?-? 69.631 21.549 ?-? 69.598 69.579 ?-? 69.597 68.696 ?-? 69.509 22.225 ?-? 69.229 69.219 ?-? 69.128 22.712 ?-? 69.034 21.551 ?-? 68.963 68.974 ?-? 68.901 21.683 ?-? 68.921 20.896 ?-? 68.844 68.876 ?-? 68.749 68.749 ?-? 68.748 21.91 ?-? 68.671 18.006 ?-? 68.634 69.52 ?-? 68.559 22.079 ?-? 68.085 66.674 ?-? 67.953 67.904 ?-? 67.422 67.419 ?-? 67.169 67.171 ?-? 67.127 57.676 ?-? 66.651 66.79 ?-? 66.322 66.356 ?-? 66.362 58.542 ?-? 66.162 21.197 ?-? 66.048 32.155 ?-? 66.014 22.904 ?-? 65.886 58.136 ?-? 65.816 65.826 ?-? 65.731 21.783 ?-? 65.252 63.073 ?-? 65.223 56.603 ?-? 65.059 65.06 ?-? 65.049 57.047 ?-? 64.986 56.339 ?-? 64.765 55.744 ?-? 64.694 17.946 ?-? 64.664 59.372 ?-? 64.655 55.658 ?-? 64.556 68.681 ?-? 64.559 64.505 ?-? 64.438 59.725 ?-? 64.416 27.328 ?-? 64.043 36.383 ?-? 64.008 32.136 ?-? 63.807 21.831 ?-? 63.733 63.74 ?-? 63.745 22.803 ?-? 63.729 17.979 ?-? 63.542 31.503 ?-? 63.563 30.78 ?-? 63.532 21.512 ?-? 63.492 72.365 ?-? 63.462 28.247 ?-? 63.336 28.094 ?-? 63.377 21.645 ?-? 63.28 72.111 ?-? 63.298 63.28 ?-? 63.292 59.093 ?-? 63.311 22.12 ?-? 63.235 57.737 ?-? 63.221 21.708 ?-? 63.154 50.745 ?-? 63.156 28.435 ?-? 63.078 32.595 ?-? 63.115 27.708 ?-? 63.02 41.133 ?-? 63.062 16.999 ?-? 62.948 28.24 ?-? 62.917 16.725 ?-? 62.847 32.424 ?-? 62.828 31.663 ?-? 62.86 21.89 ?-? 62.719 16.551 ?-? 62.618 31.498 ?-? 62.616 26.515 ?-? 62.364 62.381 ?-? 62.404 49.878 ?-? 62.414 32.908 ?-? 62.412 28.174 ?-? 62.324 75.113 ?-? 62.324 33.459 ?-? 62.303 12.156 ?-? 62.309 8.277 ?-? 62.252 23.611 ?-? 62.293 23.089 ?-? 62.2 70.308 ?-? 62.114 32.638 ?-? 62.166 28.354 ?-? 62.09 72.181 ?-? 62.052 69.93 ?-? 62.056 62.046 ?-? 62.018 70.404 ?-? 61.997 21.795 ?-? 62.013 20.895 ?-? 61.963 71.422 ?-? 61.923 69.653 ?-? 61.956 61.968 ?-? 61.859 33.34 ?-? 61.891 21.756 ?-? 61.773 33.836 ?-? 61.77 21.668 ?-? 61.681 61.689 ?-? 61.6 19.74 ?-? 61.554 61.543 ?-? 61.55 33.654 ?-? 61.497 70.392 ?-? 61.453 69.064 ?-? 61.422 22.605 ?-? 61.14 61.175 ?-? 61.139 20.602 ?-? 61.072 70.603 ?-? 61.073 21.86 ?-? 61.028 72.393 ?-? 61.024 61.067 ?-? 60.891 34.956 ?-? 60.875 49.296 ?-? 60.763 60.788 ?-? 60.77 20.413 ?-? 60.626 34.745 ?-? 60.654 34.35 ?-? 60.632 33.127 ?-? 60.679 23.409 ?-? 60.596 57.277 ?-? 60.615 16.317 ?-? 60.549 23.093 ?-? 60.499 21.374 ?-? 60.362 72.286 ?-? 60.34 42.028 ?-? 60.341 23.265 ?-? 60.34 21.256 ?-? 60.209 60.182 ?-? 60.158 35.67 ?-? 59.794 16.727 ?-? 59.347 32.415 ?-? 59.328 18.64 ?-? 59.291 71.307 ?-? 59.241 70.735 ?-? 59.228 32.168 ?-? 59.155 63.334 ?-? 59.156 59.153 ?-? 59.171 31.696 ?-? 59.158 22.344 ?-? 59.065 59.063 ?-? 59.034 19.282 ?-? 58.944 36.42 ?-? 58.903 58.885 ?-? 58.912 26.224 ?-? 58.928 18.609 ?-? 58.811 36.54 ?-? 58.851 28.497 ?-? 58.835 22.271 ?-? 58.76 58.765 ?-? 58.786 41.473 ?-? 58.788 19.415 ?-? 58.779 18.69 ?-? 58.708 66.294 ?-? 58.724 43.335 ?-? 58.696 41.964 ?-? 58.701 26.982 ?-? 58.639 58.653 ?-? 58.563 66.223 ?-? 58.603 42.073 ?-? 58.485 68.777 ?-? 58.364 21.757 ?-? 58.347 44.49 ?-? 58.311 17.732 ?-? 58.274 15.816 ?-? 58.18 58.2 ?-? 58.011 65.769 ?-? 57.904 41.673 ?-? 57.946 32.337 ?-? 57.951 27.417 ?-? 57.858 44.789 ?-? 57.807 29.288 ?-? 57.802 28.315 ?-? 57.786 25.004 ?-? 57.755 63.231 ?-? 57.723 57.72 ?-? 57.753 41.203 ?-? 57.734 30.963 ?-? 57.707 67.139 ?-? 57.69 62.007 ?-? 57.697 23.563 ?-? 57.643 57.639 ?-? 57.47 42.015 ?-? 57.417 60.083 ?-? 57.371 57.329 ?-? 57.38 41.497 ?-? 57.291 30.525 ?-? 57.262 29.863 ?-? 57.23 41.45 ?-? 57.195 31.674 ?-? 57.162 57.147 ?-? 57.164 30.915 ?-? 57.037 57.012 ?-? 57.034 30.859 ?-? 57.019 27.092 ?-? 56.995 65.042 ?-? 56.971 40.756 ?-? 56.919 56.888 ?-? 56.93 18.401 ?-? 56.799 29.722 ?-? 56.532 65.042 ?-? 56.492 42.866 ?-? 56.358 56.36 ?-? 56.257 35.133 ?-? 56.213 45.905 ?-? 56.114 41.979 ?-? 56.046 56.033 ?-? 55.969 42.688 ?-? 55.85 64.654 ?-? 55.861 39.896 ?-? 55.893 29.633 ?-? 55.775 55.764 ?-? 55.688 64.51 ?-? 55.471 55.447 ?-? 55.396 48.118 ?-? 55.404 40.115 ?-? 55.286 41.26 ?-? 55.303 31.231 ?-? 55.219 33.058 ?-? 55.155 24.694 ?-? 55.089 33.178 ?-? 55.121 29.414 ?-? 55.05 55.018 ?-? 55.023 31.555 ?-? 55.017 25.459 ?-? 54.948 39.961 ?-? 54.935 33.837 ?-? 54.869 41.275 ?-? 54.867 35.292 ?-? 54.919 34.295 ?-? 54.835 54.804 ?-? 54.794 30.194 ?-? 54.736 24.522 ?-? 54.666 44.054 ?-? 54.652 36.781 ?-? 54.657 24.575 ?-? 54.659 21.721 ?-? 54.55 40.57 ?-? 54.582 34.959 ?-? 54.537 35.602 ?-? 54.52 33.807 ?-? 54.513 33.121 ?-? 54.48 32.299 ?-? 54.49 29.501 ?-? 54.506 24.184 ?-? 54.434 54.416 ?-? 54.413 41.709 ?-? 54.431 36.256 ?-? 54.434 34.533 ?-? 54.433 27.304 ?-? 54.395 43.834 ?-? 54.41 37.017 ?-? 54.302 42.278 ?-? 54.326 41.111 ?-? 54.308 32.554 ?-? 54.303 25.769 ?-? 54.324 23.822 ?-? 54.331 23.205 ?-? 54.304 18.728 ?-? 54.268 24.318 ?-? 54.174 44.762 ?-? 54.183 43.094 ?-? 54.198 35.785 ?-? 54.216 31.916 ?-? 54.179 26.225 ?-? 54.207 23.956 ?-? 54.118 40.981 ?-? 54.109 40.65 ?-? 54.097 27.627 ?-? 54.125 26.636 ?-? 54.091 21.118 ?-? 54.08 24.037 ?-? 53.993 42.398 ?-? 53.996 41.437 ?-? 53.982 32.757 ?-? 53.932 42.93 ?-? 53.85 24.247 ?-? 53.857 13.037 ?-? 53.826 64.715 ?-? 53.826 53.795 ?-? 53.752 42.208 ?-? 53.672 53.66 ?-? 53.673 34.673 ?-? 53.573 42.56 ?-? 53.521 33.047 ?-? 53.493 68.529 ?-? 53.494 36.161 ?-? 53.484 34.777 ?-? 53.437 53.398 ?-? 53.439 42.396 ?-? 53.424 35.213 ?-? 53.41 26.807 ?-? 53.372 35.639 ?-? 53.372 25.02 ?-? 53.288 36.388 ?-? 53.239 53.242 ?-? 53.245 42.282 ?-? 53.213 27.08 ?-? 53.092 53.106 ?-? 52.861 31.804 ?-? 52.776 26.351 ?-? 52.532 52.537 ?-? 52.493 19.189 ?-? 52.47 39.767 ?-? 52.378 40.88 ?-? 52.065 52.049 ?-? 51.906 51.897 ?-? 51.883 62.478 ?-? 51.873 33.354 ?-? 51.86 19.197 ?-? 51.773 55.186 ?-? 51.783 38.503 ?-? 51.813 28.187 ?-? 51.276 32.079 ?-? 51.206 27.182 ?-? 51.174 64.324 ?-? 51.126 63.953 ?-? 51.078 23.278 ?-? 50.936 50.945 ?-? 50.981 21.127 ?-? 50.822 50.833 ?-? 50.815 32.58 ?-? 50.815 28.401 ?-? 50.739 63.086 ?-? 50.762 28.044 ?-? 50.713 20.692 ?-? 50.636 65.251 ?-? 50.639 63.357 ?-? 50.656 31.516 ?-? 50.538 65.469 ?-? 50.35 8.216 ?-? 50.32 13.462 ?-? 50.037 24.037 ?-? 50.032 23.299 ?-? 49.9 49.973 ?-? 49.728 49.731 ?-? 49.678 23.752 ?-? 49.39 49.444 ?-? 49.243 77.767 ?-? 48.527 48.482 ?-? 48.387 55.409 ?-? 48.353 48.316 ?-? 48.122 47.841 ?-? 47.421 47.585 ?-? 46.997 46.986 ?-? 47.036 37.711 ?-? 46.849 55.089 ?-? 46.849 24.174 ?-? 46.668 55.303 ?-? 46.626 63.416 ?-? 46.015 45.944 ?-? 45.809 45.747 ?-? 45.704 56.242 ?-? 45.669 69.709 ?-? 45.314 27.103 ?-? 45.309 21.662 ?-? 45.285 45.24 ?-? 45.221 23.49 ?-? 45.162 45.128 ?-? 45.073 17.704 ?-? 44.984 26.322 ?-? 44.857 44.77 ?-? 44.673 54.208 ?-? 44.667 27.265 ?-? 44.568 54.257 ?-? 44.46 44.499 ?-? 44.431 54.822 ?-? 44.26 59.148 ?-? 44.082 54.527 ?-? 44.007 28.507 ?-? 44.056 21.099 ?-? 43.976 43.953 ?-? 43.906 55.021 ?-? 43.696 53.994 ?-? 43.691 27.298 ?-? 43.693 26.25 ?-? 43.31 58.413 ?-? 43.311 43.3 ?-? 43.333 27.115 ?-? 43.347 26.771 ?-? 43.286 26.404 ?-? 43.209 24.326 ?-? 43.115 58.109 ?-? 43.098 54.327 ?-? 43.156 29.217 ?-? 43.107 27.734 ?-? 43.129 26.282 ?-? 43.111 25.896 ?-? 43.154 15.782 ?-? 42.93 55.643 ?-? 42.885 54.121 ?-? 42.648 20.298 ?-? 42.617 28.581 ?-? 42.543 26.933 ?-? 42.475 20.954 ?-? 42.398 53.734 ?-? 42.352 37.097 ?-? 42.338 25.695 ?-? 42.348 22.31 ?-? 42.295 26.773 ?-? 42.208 55.765 ?-? 42.22 42.203 ?-? 42.21 40.994 ?-? 42.226 29.567 ?-? 42.239 25.074 ?-? 42.156 56.138 ?-? 42.152 32.564 ?-? 42.164 24.771 ?-? 42.115 54.433 ?-? 42.092 21.938 ?-? 42.01 28.469 ?-? 42.052 26.458 ?-? 41.977 58.717 ?-? 41.941 57.453 ?-? 41.933 53.458 ?-? 41.87 28.589 ?-? 41.899 18.663 ?-? 41.864 23.641 ?-? 41.719 57.767 ?-? 41.688 54.55 ?-? 41.682 54.258 ?-? 41.71 27.36 ?-? 41.527 54.69 ?-? 41.437 57.15 ?-? 41.454 41.431 ?-? 41.354 18.756 ?-? 41.337 57.396 ?-? 41.334 28.745 ?-? 41.23 41.213 ?-? 41.171 55.062 ?-? 41.199 29.294 ?-? 41.034 27.741 ?-? 40.93 25.538 ?-? 40.838 54.773 ?-? 40.845 27.462 ?-? 40.805 58.534 ?-? 40.807 40.785 ?-? 40.741 52.489 ?-? 40.768 25.802 ?-? 40.688 54.394 ?-? 40.683 17.65 ?-? 40.397 40.38 ?-? 40.141 55.889 ?-? 40.066 54.922 ?-? 39.975 39.952 ?-? 39.927 55.62 ?-? 39.898 55.16 ?-? 39.776 56.035 ?-? 39.725 35.248 ?-? 39.252 39.239 ?-? 38.894 38.875 ?-? 38.799 36.679 ?-? 38.513 38.53 ?-? 38.305 38.369 ?-? 38.004 27.082 ?-? 37.904 56.76 ?-? 37.885 18.323 ?-? 37.848 37.803 ?-? 37.849 29.633 ?-? 37.706 73.97 ?-? 37.678 29.166 ?-? 37.628 63.186 ?-? 37.629 16.993 ?-? 37.665 13.992 ?-? 37.494 57.497 ?-? 37.174 37.099 ?-? 37.116 57.211 ?-? 37.033 54.428 ?-? 37.029 37 ?-? 37.059 25.77 ?-? 36.963 25.534 ?-? 36.896 36.882 ?-? 36.66 33.86 ?-? 36.624 53.287 ?-? 36.556 22.273 ?-? 36.548 19.279 ?-? 36.499 58.862 ?-? 36.483 36.464 ?-? 36.334 54.351 ?-? 36.228 33.758 ?-? 35.976 57.546 ?-? 35.884 30.449 ?-? 35.817 54.323 ?-? 35.742 59.992 ?-? 35.743 35.722 ?-? 35.771 34.979 ?-? 35.754 21.247 ?-? 35.666 20.287 ?-? 35.637 54.422 ?-? 35.658 23.867 ?-? 35.569 34.356 ?-? 35.465 54.57 ?-? 35.365 60.817 ?-? 35.128 59.44 ?-? 35.01 60.711 ?-? 34.836 23.014 ?-? 34.764 53.641 ?-? 34.791 53.272 ?-? 34.776 34.77 ?-? 34.788 33.136 ?-? 34.812 32.595 ?-? 34.804 20.413 ?-? 34.668 53.235 ?-? 34.534 21.352 ?-? 34.373 60.649 ?-? 34.356 23.4 ?-? 34.32 20.713 ?-? 34.268 34.278 ?-? 34.195 54.902 ?-? 34.174 22.18 ?-? 34.157 19.74 ?-? 34.074 61.671 ?-? 34.034 20.744 ?-? 33.803 54.379 ?-? 33.723 25.366 ?-? 33.717 36.519 ?-? 33.693 33.684 ?-? 33.706 22.473 ?-? 33.683 19.888 ?-? 33.612 61.704 ?-? 33.582 54.579 ?-? 33.521 28.057 ?-? 33.441 51.925 ?-? 33.44 30.31 ?-? 33.388 54.775 ?-? 33.397 28.293 ?-? 33.317 62.249 ?-? 33.256 60.586 ?-? 33.207 20.356 ?-? 33.197 60.732 ?-? 33.178 55.161 ?-? 33.202 53.735 ?-? 33.18 34.697 ?-? 33.175 33.157 ?-? 33.199 30.024 ?-? 33.186 20.835 ?-? 33.095 34.947 ?-? 32.985 54.651 ?-? 32.919 61.991 ?-? 32.934 53.94 ?-? 32.688 54.331 ?-? 32.729 23.006 ?-? 32.668 62.985 ?-? 32.627 62.514 ?-? 32.626 50.75 ?-? 32.63 32.626 ?-? 32.684 23.668 ?-? 32.561 28.304 ?-? 32.517 32.513 ?-? 32.399 57.39 ?-? 32.41 51.187 ?-? 32.395 29.713 ?-? 32.376 26.697 ?-? 32.399 26.012 ?-? 32.308 59.335 ?-? 32.342 54.173 ?-? 32.255 32.236 ?-? 32.281 27.237 ?-? 32.287 21.222 ?-? 32.205 66.119 ?-? 32.17 64.318 ?-? 32.128 50.955 ?-? 32.113 22.854 ?-? 31.983 18.015 ?-? 31.944 62.478 ?-? 31.97 52.873 ?-? 31.924 36.586 ?-? 31.956 6.343 ?-? 31.867 63.629 ?-? 31.756 28.457 ?-? 31.638 65.354 ?-? 31.612 62.686 ?-? 31.63 16.624 ?-? 31.541 50.621 ?-? 31.532 21.778 ?-? 31.552 16.847 ?-? 31.463 62.783 ?-? 31.46 16.51 ?-? 31.456 63.3 ?-? 31.431 31.409 ?-? 31.438 28.11 ?-? 31.294 56.378 ?-? 31.298 55.073 ?-? 31.318 31.318 ?-? 31.326 24.812 ?-? 31.218 63.09 ?-? 31.14 57.722 ?-? 31.152 23.579 ?-? 31.089 25.044 ?-? 31.051 27.393 ?-? 30.97 41.623 ?-? 30.934 57.57 ?-? 30.864 55.926 ?-? 30.768 30.715 ?-? 30.704 63.334 ?-? 30.735 21.678 ?-? 30.678 63.682 ?-? 30.573 30.557 ?-? 30.513 63.582 ?-? 30.548 36.921 ?-? 30.463 30.459 ?-? 30.423 57.179 ?-? 30.346 30.325 ?-? 30.216 54.698 ?-? 30.152 33.375 ?-? 29.884 56.928 ?-? 29.893 55.852 ?-? 29.836 55.365 ?-? 29.734 32.398 ?-? 29.714 26.333 ?-? 29.695 25.774 ?-? 29.559 42.193 ?-? 29.41 56.054 ?-? 29.435 14.125 ?-? 29.361 29.338 ?-? 29.344 24.916 ?-? 29.342 16.961 ?-? 29.29 57.804 ?-? 29.273 24.046 ?-? 29.189 41.209 ?-? 29.181 15.764 ?-? 29.036 58.069 ?-? 29.025 25.42 ?-? 28.941 32.128 ?-? 28.998 28.97 ?-? 28.83 23.764 ?-? 28.752 41.851 ?-? 28.582 28.563 ?-? 28.538 31.995 ?-? 28.456 62.969 ?-? 28.45 58.833 ?-? 28.475 32.518 ?-? 28.458 28.453 ?-? 28.461 18.688 ?-? 28.424 13.315 ?-? 28.378 50.762 ?-? 28.317 62.514 ?-? 28.312 58.513 ?-? 28.209 63.408 ?-? 28.185 62.39 ?-? 28.21 51.857 ?-? 28.215 33.385 ?-? 28.138 31.542 ?-? 27.817 27.785 ?-? 27.796 24.245 ?-? 27.715 54.176 ?-? 27.759 43.006 ?-? 27.747 25.973 ?-? 27.694 41.061 ?-? 27.651 25.622 ?-? 27.452 23.582 ?-? 27.427 57.763 ?-? 27.396 41.504 ?-? 27.422 31.135 ?-? 27.403 22.738 ?-? 27.33 41.853 ?-? 27.361 27.337 ?-? 27.323 23.171 ?-? 27.275 64.357 ?-? 27.287 57.093 ?-? 27.3 54.421 ?-? 27.283 53.488 ?-? 27.277 51.22 ?-? 27.293 44.602 ?-? 27.278 32.09 ?-? 27.23 27.198 ?-? 27.216 24.489 ?-? 27.142 45.132 ?-? 27.128 44.816 ?-? 27.147 41.952 ?-? 27.176 26.34 ?-? 27.165 25.619 ?-? 27.128 21.592 ?-? 27.151 18.332 ?-? 27.119 53.012 ?-? 27.121 42.391 ?-? 27.066 37.841 ?-? 27.013 56.714 ?-? 27.001 43.479 ?-? 26.995 24.306 ?-? 26.94 12.331 ?-? 26.824 58.844 ?-? 26.842 26.828 ?-? 26.821 25.06 ?-? 26.759 42.188 ?-? 26.744 22.317 ?-? 26.693 53.412 ?-? 26.704 43.239 ?-? 26.642 26.612 ?-? 26.556 23.764 ?-? 26.534 53.888 ?-? 26.483 53.079 ?-? 26.533 52.762 ?-? 26.496 43.772 ?-? 26.537 26.533 ?-? 26.391 53.962 ?-? 26.354 44.751 ?-? 26.373 27.139 ?-? 26.342 21.588 ?-? 26.257 45.182 ?-? 26.243 42.98 ?-? 26.263 23.185 ?-? 26.212 27.349 ?-? 26.178 23.046 ?-? 26.095 27.803 ?-? 26.145 26.102 ?-? 26.057 67.229 ?-? 26.082 24.231 ?-? 26.001 59.451 ?-? 25.919 36.744 ?-? 25.906 32.507 ?-? 25.863 37.203 ?-? 25.784 54.418 ?-? 25.826 29.614 ?-? 25.707 42.342 ?-? 25.707 40.893 ?-? 25.709 27.533 ?-? 25.763 22.625 ?-? 25.742 21.869 ?-? 25.697 54.057 ?-? 25.671 53.696 ?-? 25.654 26.778 ?-? 25.682 25.647 ?-? 25.601 27.181 ?-? 25.604 24.573 ?-? 25.54 28.974 ?-? 25.543 12.119 ?-? 25.476 33.863 ?-? 25.432 54.995 ?-? 25.355 36.925 ?-? 25.068 42.053 ?-? 25.105 26.829 ?-? 25.09 25.063 ?-? 25.081 22.312 ?-? 25.02 57.711 ?-? 25.02 42.168 ?-? 24.936 30.908 ?-? 24.886 35.128 ?-? 24.921 29.333 ?-? 24.842 31.215 ?-? 24.781 55.043 ?-? 24.508 32.727 ?-? 24.45 43.865 ?-? 24.423 21.671 ?-? 24.364 43.388 ?-? 24.336 54.439 ?-? 24.291 27.072 ?-? 24.244 43.514 ?-? 24.256 43.032 ?-? 24.243 27.78 ?-? 24.251 24.226 ?-? 24.154 54.073 ?-? 24.18 26.055 ?-? 24.081 54.189 ?-? 24.008 23.959 ?-? 23.923 28.702 ?-? 23.857 54.412 ?-? 23.864 49.68 ?-? 23.832 26.573 ?-? 23.796 28.839 ?-? 23.811 23.789 ?-? 23.739 52.547 ?-? 23.678 57.755 ?-? 23.64 32.696 ?-? 23.693 23.671 ?-? 23.604 57.913 ?-? 23.62 41.714 ?-? 23.633 30.987 ?-? 23.513 27.372 ?-? 23.538 23.509 ?-? 23.398 34.207 ?-? 23.426 21.411 ?-? 23.33 60.685 ?-? 23.306 51.025 ?-? 23.201 54.288 ?-? 23.24 50.155 ?-? 23.213 49.903 ?-? 23.216 44.705 ?-? 23.202 26.185 ?-? 23.224 23.186 ?-? 23.068 70.286 ?-? 23.1 54.087 ?-? 23.104 34.733 ?-? 23.067 32.761 ?-? 23.095 23.063 ?-? 23.034 62.179 ?-? 22.971 34.847 ?-? 22.974 22.945 ?-? 22.961 21.192 ?-? 22.916 66.059 ?-? 22.891 32.125 ?-? 22.883 18.017 ?-? 22.842 22.807 ?-? 22.768 63.75 ?-? 22.697 69.095 ?-? 22.7 22.667 ?-? 22.643 61.408 ?-? 22.653 27.723 ?-? 22.648 27.419 ?-? 22.643 25.726 ?-? 22.574 22.538 ?-? 22.504 70 ?-? 22.53 33.63 ?-? 22.498 19.865 ?-? 22.428 73.056 ?-? 22.463 59.327 ?-? 22.382 70.127 ?-? 22.359 42.282 ?-? 22.392 42.034 ?-? 22.38 22.351 ?-? 22.329 58.78 ?-? 22.312 26.807 ?-? 22.331 25.04 ?-? 22.339 19.254 ?-? 22.238 69.484 ?-? 22.272 36.5 ?-? 22.267 22.242 ?-? 22.163 67.963 ?-? 22.193 63.38 ?-? 22.14 22.11 ?-? 22.052 68.625 ?-? 22.054 68.227 ?-? 22.061 60.339 ?-? 21.962 72.211 ?-? 21.926 61.097 ?-? 21.861 70.66 ?-? 21.839 65.862 ?-? 21.844 62.952 ?-? 21.829 61.987 ?-? 21.87 58.199 ?-? 21.864 53.541 ?-? 21.887 25.692 ?-? 21.82 63.769 ?-? 21.807 61.218 ?-? 21.764 31.564 ?-? 21.82 16.566 ?-? 21.74 30.718 ?-? 21.737 21.704 ?-? 21.649 69.67 ?-? 21.695 61.672 ?-? 21.691 61.325 ?-? 21.674 30.453 ?-? 21.61 68.938 ?-? 21.611 52.919 ?-? 21.622 27.102 ?-? 21.578 26.329 ?-? 21.618 24.327 ?-? 21.62 21.591 ?-? 21.528 63.527 ?-? 21.477 54.46 ?-? 21.493 21.462 ?-? 21.384 59.937 ?-? 21.39 34.417 ?-? 21.422 23.409 ?-? 21.352 21.323 ?-? 21.267 60.344 ?-? 21.28 35.683 ?-? 21.284 20.293 ?-? 21.195 65.971 ?-? 21.207 51.067 ?-? 21.21 32.17 ?-? 21.231 22.896 ?-? 21.237 21.212 ?-? 21.083 71.46 ?-? 20.999 68.767 ?-? 20.982 62.002 ?-? 20.973 20.946 ?-? 20.838 33.135 ?-? 20.845 20.819 ?-? 20.749 61.624 ?-? 20.754 19.671 ?-? 20.706 72.384 ?-? 20.688 70.418 ?-? 20.677 61.163 ?-? 20.68 34.057 ?-? 20.589 20.548 ?-? 20.427 60.791 ?-? 20.447 33.238 ?-? 20.389 56.759 ?-? 20.361 35.772 ?-? 20.388 20.362 ?-? 20.331 60.076 ?-? 20.037 20.016 ?-? 19.923 22.478 ?-? 19.906 19.886 ?-? 19.864 33.85 ?-? 19.781 61.69 ?-? 19.72 34.091 ?-? 19.71 20.692 ?-? 19.621 19.62 ?-? 19.347 58.813 ?-? 19.333 36.557 ?-? 19.338 19.313 ?-? 19.242 70.774 ?-? 19.253 51.9 ?-? 19.288 22.301 ?-? 18.727 58.819 ?-? 18.784 7.077 ?-? 18.702 41.946 ?-? 18.625 71.338 ?-? 18.657 28.406 ?-? 18.643 18.62 ?-? 18.56 53.223 ?-? 18.513 59.173 ?-? 18.456 18.438 ?-? 18.365 57.027 ?-? 18.397 37.846 ?-? 18.336 27.07 ?-? 18.346 12.36 ?-? 18.327 63.923 ?-? 18.321 38.011 ?-? 18.109 21.202 ?-? 18.024 63.679 ?-? 18.038 40.803 ?-? 18.02 31.938 ?-? 18.048 22.74 ?-? 18.05 18.02 ?-? 17.993 64.57 ?-? 17.914 68.636 ?-? 17.865 40.859 ?-? 17.736 58.388 ?-? 17.735 25.486 ?-? 17.29 63.213 ?-? 17.108 75.714 ?-? 17.059 37.624 ?-? 17.033 29.303 ?-? 17.004 14.163 ?-? 16.872 63.027 ?-? 16.877 16.864 ?-? 16.671 31.602 ?-? 16.636 21.746 ?-? 16.573 62.67 ?-? 16.577 31.477 ?-? 15.819 43.143 ?-? 15.78 58.299 ?-? 15.791 29.203 ?-? 15.792 15.756 ?-? 15.397 54.057 ?-? 14.307 63.577 ?-? 14.217 37.574 ?-? 14.243 29.295 ?-? 14.208 17.014 ?-? 14.234 14.21 ?-? 13.897 13.929 ?-? 13.321 28.456 ?-? 13.29 13.27 ?-? 12.882 12.88 ?-? 12.747 12.739 ?-? 12.373 37.786 ?-? 12.344 26.964 ?-? 12.271 18.319 ?-? 12.246 12.222 ?-? 12.164 25.395 ?-? 12.045 23.084 ?-? 11.656 26.206 ?-? 9.771 66.973 ?-? 184.129 34.747 ?-? 184.088 53.739 ?-? 183.776 38.971 ?-? 183.663 69.717 ?-? 183.265 55.922 ?-? 183.228 36.371 ?-? 183.162 53.309 ?-? 183.051 12.826 ?-? 182.829 36.93 ?-? 182.632 35.638 ?-? 182.244 35.943 ?-? 181.575 70.773 ?-? 180.807 29.681 ?-? 180.539 33.208 ?-? 180.314 54.559 ?-? 180.042 40.605 ?-? 180.043 29.493 ?-? 179.991 54.357 ?-? 179.992 41.667 ?-? 179.942 39.958 ?-? 179.957 34.232 ?-? 179.868 32.798 ?-? 179.865 20.092 ?-? 179.607 54.932 ?-? 179.629 39.696 ?-? 179.547 65.156 ?-? 179.481 57.341 ?-? 179.456 41.161 ?-? 179.414 41.532 ?-? 179.432 33.579 ?-? 179.364 43.502 ?-? 179.345 42.183 ?-? 179.28 62.956 ?-? 179.293 57.093 ?-? 179.228 58.691 ?-? 179.213 56.984 ?-? 179.152 32.532 ?-? 179.103 57.381 ?-? 178.963 55.003 ?-? 178.617 54.636 ?-? 178.516 54.201 ?-? 178.41 40.429 ?-? 178.329 57.217 ?-? 178.204 59.064 ?-? 178.18 36.878 ?-? 178.196 21.827 ?-? 178.109 32.436 ?-? 178.036 66.986 ?-? 178.035 42.156 ?-? 178.063 21.766 ?-? 177.981 57.923 ?-? 177.976 31.472 ?-? 177.933 56.729 ?-? 177.941 54.352 ?-? 177.96 36.468 ?-? 177.701 50.76 ?-? 177.703 28.114 ?-? 177.656 22.719 ?-? 177.617 63.318 ?-? 177.6 56.914 ?-? 177.639 53.399 ?-? 177.609 31.63 ?-? 177.481 56.793 ?-? 177.456 54.969 ?-? 177.488 32.139 ?-? 177.416 66.039 ?-? 177.411 64.542 ?-? 177.32 51.075 ?-? 177.339 23.125 ?-? 177.229 22.32 ?-? 177.23 21.172 ?-? 177.169 53.597 ?-? 177.183 38.621 ?-? 177.075 63.261 ?-? 177.078 41.724 ?-? 177.033 57.678 ?-? 177 54.707 ?-? 177.05 27.226 ?-? 177.02 24.972 ?-? 177.049 23.392 ?-? 176.935 56.96 ?-? 176.934 31.035 ?-? 176.895 63.322 ?-? 176.876 60.969 ?-? 176.886 53.177 ?-? 176.898 23.292 ?-? 176.844 57.939 ?-? 176.817 43.284 ?-? 176.853 30.866 ?-? 176.772 54.947 ?-? 176.731 63.437 ?-? 176.693 57.468 ?-? 176.688 54.252 ?-? 176.705 32.993 ?-? 176.709 27.522 ?-? 176.691 24.328 ?-? 176.552 59.456 ?-? 176.605 53.95 ?-? 176.594 42.17 ?-? 176.491 34.408 ?-? 176.436 43.663 ?-? 176.411 26.923 ?-? 176.326 57.687 ?-? 176.323 32.53 ?-? 176.242 63.256 ?-? 176.249 54.401 ?-? 176.239 32.001 ?-? 176.264 30.566 ?-? 176.268 20.377 ?-? 176.189 60.766 ?-? 176.17 57.215 ?-? 176.209 56.25 ?-? 176.198 35.629 ?-? 176.204 30.26 ?-? 176.129 59.125 ?-? 176.12 43.274 ?-? 176.062 56.408 ?-? 176.015 60.595 ?-? 175.968 46.976 ?-? 175.967 39.999 ?-? 175.989 39.768 ?-? 175.956 35.746 ?-? 175.905 18.748 ?-? 175.859 63.105 ?-? 175.852 54.943 ?-? 175.846 42.818 ?-? 175.876 33.875 ?-? 175.767 54.357 ?-? 175.782 31.338 ?-? 175.826 23.022 ?-? 175.822 17.4 ?-? 175.705 42.884 ?-? 175.71 32.75 ?-? 175.72 21.113 ?-? 175.751 19.249 ?-? 175.697 55.982 ?-? 175.645 26.67 ?-? 175.598 53.491 ?-? 175.613 52.052 ?-? 175.611 50.903 ?-? 175.606 49.685 ?-? 175.579 47.314 ?-? 175.581 42.931 ?-? 175.626 40.559 ?-? 175.59 34.946 ?-? 175.607 21.503 ?-? 175.567 63.472 ?-? 175.559 60.942 ?-? 175.546 56.978 ?-? 175.547 54.63 ?-? 175.529 41.53 ?-? 175.509 30.979 ?-? 175.564 24.14 ?-? 175.548 21.195 ?-? 175.526 17.958 ?-? 175.486 61.856 ?-? 175.499 57.66 ?-? 175.483 55.716 ?-? 175.483 52.436 ?-? 175.445 44.906 ?-? 175.451 32.34 ?-? 175.474 23.838 ?-? 175.425 57.053 ?-? 175.435 54.079 ?-? 175.381 53.76 ?-? 175.442 40.671 ?-? 175.409 39.835 ?-? 175.406 32.013 ?-? 175.333 33.448 ?-? 175.321 32.924 ?-? 175.263 34.677 ?-? 175.297 34.296 ?-? 175.195 54.973 ?-? 175.233 50.978 ?-? 175.248 42.497 ?-? 175.197 31.825 ?-? 175.248 31.216 ?-? 175.24 27.118 ?-? 175.221 21.434 ?-? 175.135 53.288 ?-? 175.147 41.794 ?-? 175.182 23.347 ?-? 175.123 20.875 ?-? 175.148 19.837 ?-? 175.058 59.203 ?-? 175.098 52.887 ?-? 174.995 64.169 ?-? 174.993 57.645 ?-? 175.012 33.677 ?-? 175.009 27.05 ?-? 174.996 26.445 ?-? 174.976 52.098 ?-? 174.909 67.367 ?-? 174.904 65.058 ?-? 174.92 58.795 ?-? 174.87 56.877 ?-? 174.891 52.65 ?-? 174.922 41.274 ?-? 174.873 20.681 ?-? 174.804 67.109 ?-? 174.818 40.611 ?-? 174.809 33.868 ?-? 174.81 22.54 ?-? 174.752 65.154 ?-? 174.769 61.622 ?-? 174.786 56.383 ?-? 174.785 52.571 ?-? 174.734 31.462 ?-? 174.687 62.103 ?-? 174.682 51.76 ?-? 174.687 43.927 ?-? 174.676 41.941 ?-? 174.648 61.174 ?-? 174.609 33.36 ?-? 174.626 28.126 ?-? 174.626 27.243 ?-? 174.57 64.709 ?-? 174.563 62.272 ?-? 174.598 57.219 ?-? 174.542 55.916 ?-? 174.592 55.516 ?-? 174.574 54.472 ?-? 174.598 53.082 ?-? 174.556 41.886 ?-? 174.54 26.491 ?-? 174.58 23.801 ?-? 174.586 21.791 ?-? 174.519 40.844 ?-? 174.449 69.109 ?-? 174.449 43.62 ?-? 174.429 19.077 ?-? 174.348 63.463 ?-? 174.362 61.931 ?-? 174.397 59.446 ?-? 174.374 54.198 ?-? 174.407 36.439 ?-? 174.399 29.22 ?-? 174.368 20.981 ?-? 174.287 64.457 ?-? 174.28 58.87 ?-? 174.332 56.303 ?-? 174.318 55.683 ?-? 174.286 54.847 ?-? 174.314 34.302 ?-? 174.329 33.589 ?-? 174.23 71.37 ?-? 174.219 68.565 ?-? 174.275 62.969 ?-? 174.249 62.058 ?-? 174.218 59.069 ?-? 174.224 52.88 ?-? 174.229 44.756 ?-? 174.261 27.92 ?-? 174.242 22.729 ?-? 174.171 54.76 ?-? 174.203 42.183 ?-? 174.183 34.639 ?-? 174.168 22.178 ?-? 174.203 18.575 ?-? 174.118 53.566 ?-? 174.12 36.603 ?-? 174.047 69.612 ?-? 174.046 68.727 ?-? 174.056 41.714 ?-? 174.021 41.248 ?-? 174.045 22.872 ?-? 174.062 21.98 ?-? 174.016 62.171 ?-? 173.96 58.617 ?-? 174.012 57.81 ?-? 173.982 55.924 ?-? 173.959 55.218 ?-? 173.993 54.424 ?-? 173.959 35.653 ?-? 174.014 21.274 ?-? 173.92 64.082 ?-? 173.917 53.015 ?-? 173.909 41.886 ?-? 173.927 33.383 ?-? 173.916 31.126 ?-? 173.788 61.987 ?-? 173.804 60.206 ?-? 173.807 58.953 ?-? 173.804 34.296 ?-? 173.821 22.372 ?-? 173.72 50.756 ?-? 173.701 41.116 ?-? 173.758 21.494 ?-? 173.72 19.926 ?-? 173.696 70.387 ?-? 173.689 60.273 ?-? 173.685 58.856 ?-? 173.584 61.617 ?-? 173.582 53.17 ?-? 173.484 61.451 ?-? 173.496 56.312 ?-? 173.437 20.872 ?-? 173.338 52.059 ?-? 173.348 41.514 ?-? 173.301 62.331 ?-? 173.286 33.153 ?-? 173.187 56.118 ?-? 173.185 45.893 ?-? 173.183 38.456 ?-? 173.179 68.805 ?-? 173.159 55.533 ?-? 173.166 52.247 ?-? 173.002 64.268 ?-? 172.998 60.292 ?-? 172.963 64.681 ?-? 172.918 73.203 ?-? 172.882 55.19 ?-? 172.79 22.208 ?-? 172.694 42.774 ?-? 172.65 44.306 ?-? 172.488 71.469 ?-? 172.508 60.715 ?-? 172.527 59.902 ?-? 172.521 54.647 ?-? 172.367 56.387 ?-? 172.399 44.095 ?-? 172.315 58.896 ?-? 172.28 54.959 ?-? 172.225 66.465 ?-? 172.15 58.471 ?-? 172.084 66.093 ?-? 172.088 61.142 ?-? 172.099 21.824 ?-? 172.094 15.853 ?-? 172.045 65.774 ?-? 171.962 57.083 ?-? 172.012 53.446 ?-? 171.968 15.737 ?-? 171.919 58.182 ?-? 171.946 56.902 ?-? 171.875 57.17 ?-? 171.803 56.161 ?-? 171.643 57.813 ?-? 171.577 63.294 ?-? 171.446 63.23 ?-? 171.104 63.037 ?-? 170.932 19.11 ?-? 170.635 22.177 ?-? 170.585 63.336 ?-? 170.434 42.934 ?-? 73.029 59.318 ; loop_ _Spectral_dim.ID _Spectral_dim.Atom_type _Spectral_dim.Atom_isotope_number _Spectral_dim.Spectral_region _Spectral_dim.Magnetization_linkage_ID _Spectral_dim.Under_sampling_type _Spectral_dim.Sweep_width _Spectral_dim.Sweep_width_units _Spectral_dim.Center_frequency_offset _Spectral_dim.Encoding_code _Spectral_dim.Encoded_reduced_dimension_ID _Spectral_dim.Entry_ID _Spectral_dim.Spectral_peak_list_ID 2 C 13 CA . . 100000 Hz . . . 26891 3 stop_ save_ save_15N-13CA_UCN _Spectral_peak_list.Sf_category spectral_peak_list _Spectral_peak_list.Sf_framecode 15N-13CA_UCN _Spectral_peak_list.Entry_ID 26891 _Spectral_peak_list.ID 4 _Spectral_peak_list.Sample_ID 3 _Spectral_peak_list.Sample_label $sample_3 _Spectral_peak_list.Sample_condition_list_ID 3 _Spectral_peak_list.Sample_condition_list_label $sample_conditions_3 _Spectral_peak_list.Experiment_ID 4 _Spectral_peak_list.Experiment_name '2D 15N-13CA' _Spectral_peak_list.Number_of_spectral_dimensions 2 _Spectral_peak_list.Details . _Spectral_peak_list.Text_data_format text _Spectral_peak_list.Text_data ; Assignment w1 w2 ?-? 122.719 57.266 ?-? 119.661 56.906 ?-? 140.251 50.597 ?-? 120.27 55.521 ?-? 136.847 51.22 ?-? 121.966 62.138 ?-? 131.099 51.925 ?-? 123.494 49.665 ?-? 123.311 49.913 ?-? 117.369 59.626 ?-? 120.166 60.625 ?-? 129.42 60.965 ?-? 111.487 56.15 ?-? 85.301 45.122 ?-? 107.115 62.858 ?-? 109.664 44.302 ?-? 109.802 43.972 ?-? 110.955 47.596 ?-? 111.069 60.542 ?-? 127.734 61.594 ?-? 111.397 60.831 ?-? 120.099 53.416 ?-? 122.096 49.999 ?-? 119.742 57.395 ?-? 113.021 63.291 ?-? 118.529 58.911 ?-? 113.267 59.204 ?-? 121.041 53.643 ?-? 114.153 56.9 ?-? 124.735 57.424 ?-? 117.872 61.697 ?-? 141.896 62.588 ?-? 124.058 53.115 ?-? 123.902 57.994 ?-? 123.901 56.25 ?-? 123.735 53.937 ?-? 123.487 58.256 ?-? 104.861 64.036 ?-? 130.558 51.276 ?-? 123.915 50.973 ?-? 113.408 55.596 ?-? 117.1 53.361 ?-? 121.619 57.824 ?-? 118.944 61.151 ?-? 125.922 55.961 ?-? 117.101 53.457 ?-? 119.142 58.232 ?-? 116.647 56.95 ?-? 117.32 53.076 ?-? 126.646 60.645 ?-? 112.441 58.596 ?-? 111.728 59.365 ?-? 114.711 61.467 ?-? 124.052 54.366 ?-? 105.089 58.166 ?-? 113.155 53.567 ?-? 117.526 54.549 ?-? 130.494 55.052 ?-? 129.37 53.981 ?-? 121.459 68.653 ?-? 115.425 56.96 ?-? 107.607 63.254 ?-? 122.87 59.473 ?-? 110.469 54.42 ?-? 115.396 62.105 ?-? 117.528 55.966 ?-? 127.493 57.362 ?-? 119.126 54.327 ?-? 128.071 61.987 ?-? 123.027 54.992 ?-? 118.169 57.733 ?-? 111.975 62.003 ?-? 127.459 53.033 ?-? 114.984 55.441 ?-? 118.291 53.67 ?-? 123.222 52.304 ?-? 113.43 62.964 ?-? 112.428 55.002 ?-? 111.881 56.754 ?-? 116.134 64.631 ?-? 128.023 54.433 ?-? 122.628 53.495 ?-? 111.654 44.701 ?-? 122.367 54.155 ?-? 141.366 62.325 ?-? 111.974 62.016 ?-? 126.448 63.172 ?-? 131.852 57.699 ?-? 108.369 57.218 ?-? 120.71 63.696 ?-? 121.03 58.727 ?-? 121.007 57.244 ?-? 118.366 66.053 ?-? 115.006 60.29 ?-? 111.123 47.1 ?-? 116.407 59.145 ?-? 110.535 54.448 ?-? 117.722 57.668 ?-? 105.111 58.187 ?-? 122.159 56.331 ?-? 120.932 54.409 ?-? 125.499 54.39 ?-? 108.731 59.261 ?-? 125.585 51.073 ?-? 119.076 55.688 ?-? 114.66 59.106 ?-? 113.026 59.977 ?-? 117.323 52.199 ?-? 116.693 55.141 ?-? 130.131 51.07 ?-? 120.603 60.157 ?-? 125.644 56.936 ?-? 108.641 59.271 ?-? 128.655 57.818 ?-? 128.186 63.472 ?-? 128.155 58.618 ?-? 124.506 55.078 ?-? 126.336 61.999 ?-? 122.175 61.506 ?-? 129.107 52.819 ?-? 116.678 50.184 ?-? 115.655 56.32 ?-? 121.864 56.744 ?-? 122.912 59.488 ?-? 138.461 44.114 ?-? 128.982 56.548 ?-? 122.195 60.737 ; loop_ _Spectral_dim.ID _Spectral_dim.Atom_type _Spectral_dim.Atom_isotope_number _Spectral_dim.Spectral_region _Spectral_dim.Magnetization_linkage_ID _Spectral_dim.Under_sampling_type _Spectral_dim.Sweep_width _Spectral_dim.Sweep_width_units _Spectral_dim.Center_frequency_offset _Spectral_dim.Encoding_code _Spectral_dim.Encoded_reduced_dimension_ID _Spectral_dim.Entry_ID _Spectral_dim.Spectral_peak_list_ID 2 N-C 15 N-CA . . 100000 Hz . . . 26891 4 stop_ save_ save_15N-13C_2-gly _Spectral_peak_list.Sf_category spectral_peak_list _Spectral_peak_list.Sf_framecode 15N-13C_2-gly _Spectral_peak_list.Entry_ID 26891 _Spectral_peak_list.ID 5 _Spectral_peak_list.Sample_ID 4 _Spectral_peak_list.Sample_label $sample_4 _Spectral_peak_list.Sample_condition_list_ID 3 _Spectral_peak_list.Sample_condition_list_label $sample_conditions_3 _Spectral_peak_list.Experiment_ID 5 _Spectral_peak_list.Experiment_name '2D 15N-13CA' _Spectral_peak_list.Number_of_spectral_dimensions 2 _Spectral_peak_list.Details . _Spectral_peak_list.Text_data_format text _Spectral_peak_list.Text_data ; Assignment w1 w2 ?-? 123.229 57.742 ?-? 120.621 56.388 ?-? 120.597 54.976 ?-? 120.37 59.572 ?-? 120.005 60.125 ?-? 119.322 56.769 ?-? 118.835 57.801 ?-? 118.816 55.693 ?-? 118.8 55.177 ?-? 118.785 53.753 ?-? 118.448 60.64 ?-? 118.392 58.514 ?-? 118.346 65.471 ?-? 117.878 53.049 ?-? 117.249 57.422 ?-? 117.203 51.801 ?-? 116.617 52.91 ?-? 115.98 58.676 ?-? 116.023 54.272 ?-? 115.89 64.042 ?-? 115.918 49.489 ?-? 114.004 56.409 ?-? 113.002 53.103 ?-? 112.646 62.57 ?-? 111.504 61.465 ?-? 111.49 58.862 ?-? 111.48 43.953 ?-? 111.245 55.851 ?-? 110.915 46.371 ?-? 110.889 56.915 ?-? 109.647 43.511 ?-? 106.875 62.316 ?-? 142.746 68.048 ?-? 131.806 57.001 ?-? 130.383 57.762 ?-? 127.031 44.506 ?-? 125.16 59.635 ?-? 124.462 53.495 ?-? 122.263 54.273 ?-? 120.331 53.75 ?-? 119.958 61.014 ?-? 117.91 63.063 ?-? 104.394 53.829 ?-? 100.14 59.145 ?-? 99.15 60.739 ?-? 98.366 44.428 ?-? 130.086 54.495 ?-? 129.756 50.54 ?-? 128.25 53.929 ?-? 128.03 62.888 ?-? 127.853 61.177 ?-? 127.096 53.913 ?-? 126.22 60.033 ?-? 126.12 62.652 ?-? 126.074 53.723 ?-? 125.429 50.59 ?-? 125.313 56.391 ?-? 124.19 56.825 ?-? 123.805 54.024 ?-? 131.536 57.13 ?-? 122.976 59.021 ?-? 122.909 51.797 ?-? 122.618 56.695 ?-? 122.389 49.185 ?-? 122.027 55.9 ?-? 121.997 53.892 ?-? 121.496 56.38 ?-? 121.334 68.054 ?-? 120.901 58.059 ?-? 120.855 54.031 ?-? 120.747 56.784 ?-? 114.628 61.108 ?-? 130.813 51.363 ?-? 113.142 55.091 ?-? 125.434 55.541 ?-? 127.081 61.073 ?-? 112.21 58.217 ?-? 114.802 61.511 ?-? 104.958 57.769 ?-? 117.185 54.206 ?-? 130.512 54.686 ?-? 120.685 63.188 ?-? 119.007 56.616 ?-? 117.145 55.553 ?-? 127.457 56.978 ?-? 128.006 61.609 ?-? 111.684 61.628 ?-? 111.913 61.664 ?-? 115.067 55.23 ?-? 118.152 57.365 ?-? 127.979 58.08 ?-? 127.38 54.183 ?-? 122.758 54.616 ?-? 122.506 54.345 ?-? 108.113 56.872 ?-? 122.042 61.201 ?-? 121.744 60.085 ?-? 114.609 59.833 ?-? 123.861 57.501 ?-? 110.063 53.963 ?-? 118.903 55.273 ?-? 112.826 59.598 ?-? 117.084 52.58 ?-? 116.476 54.825 ?-? 108.457 58.781 ?-? 128.553 57.3 ?-? 124.337 54.582 ?-? 119.107 55.343 ?-? 125.979 61.638 ?-? 116.13 56.643 ?-? 115.225 56.149 ?-? 128.479 56.202 ?-? 126.977 56.663 ?-? 117.655 55.011 ?-? 114.605 54.902 ?-? 104.589 63.596 ; loop_ _Spectral_dim.ID _Spectral_dim.Atom_type _Spectral_dim.Atom_isotope_number _Spectral_dim.Spectral_region _Spectral_dim.Magnetization_linkage_ID _Spectral_dim.Under_sampling_type _Spectral_dim.Sweep_width _Spectral_dim.Sweep_width_units _Spectral_dim.Center_frequency_offset _Spectral_dim.Encoding_code _Spectral_dim.Encoded_reduced_dimension_ID _Spectral_dim.Entry_ID _Spectral_dim.Spectral_peak_list_ID 2 N-CA 15 N-CA . . 100000 Hz . . . 26891 5 stop_ save_